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Facile Oxygen Atom Insertion into Unactivated C(sp3)-C(sp2) Single Bonds in Reactions of Iridium(III) Complexes with O2

dc.creatorCristóbal Gasga, Crispín Silvanoes
dc.creatorÁlvarez González, Eleuterioes
dc.creatorPaneque Sosa, Margaritaes
dc.creatorLópez Poveda, Manueles
dc.date.accessioned2018-10-01T11:13:15Z
dc.date.available2018-10-01T11:13:15Z
dc.date.issued2013
dc.identifier.citationCristóbal Gasga, C.S., Álvarez González, E., Paneque Sosa, M. y López Poveda, M. (2013). Facile Oxygen Atom Insertion into Unactivated C(sp3)-C(sp2) Single Bonds in Reactions of Iridium(III) Complexes with O2. Organometallics, 32 (2), 714-717. https://doi.org/10.1021/om300890d.
dc.identifier.issn0276-7333 (impreso)es
dc.identifier.issn1520-6041 (electrónico)es
dc.identifier.urihttps://hdl.handle.net/11441/78946
dc.description.abstractThe Ir(III) pyridylidene TpMe2tiebar above startr(CH2CH2-o-tiebar above endC6H4)(tiebar above startCN(H)CHCHCHtiebar above endCH) (3; TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate) reacts with oxygen (air), under mild conditions, to afford a bicyclic ether-semiaminal species. The new structure derives formally from two oxidative events. One is dehydrogenative in nature (loss of 2H), and the other consists of the insertion of an oxygen atom into a nonactivated benzylic C–C bond. The reaction has been extended to a related iridacycle that contains a pyrazole coligand instead of the pyridylidene.es
dc.description.sponsorshipMinisterio de Ciencia y Tecnología CTQ2010-17476, Consolider-Ingenio 2010 CSD2007-00006es
dc.description.sponsorshipJunta de Andalucía FQM-119, P09-FQM-4832es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherAmerican Chemical Societyes
dc.relation.ispartofOrganometallics, 32 (2), 714-717.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleFacile Oxygen Atom Insertion into Unactivated C(sp3)-C(sp2) Single Bonds in Reactions of Iridium(III) Complexes with O2es
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/acceptedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Inorgánicaes
dc.relation.projectIDCTQ2010-17476es
dc.relation.projectIDConsolider-Ingenio 2010 CSD2007-00006es
dc.relation.projectIDFQM-119es
dc.relation.projectIDP09-FQM-4832es
dc.relation.publisherversionhttp://dx.doi.org/10.1021/om300890des
dc.identifier.doi10.1021/om300890des
idus.format.extent13es
dc.journaltitleOrganometallicses
dc.publication.volumen32es
dc.publication.issue2es
dc.publication.initialPage714es
dc.publication.endPage717es
dc.contributor.funderMinisterio de Ciencia y Tecnología (MCYT). España
dc.contributor.funderJunta de Andalucía

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