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Formation of C−X Bonds Through Stable Low-Electron Count Cationic Pt(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes

 

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dc.creator Rivada Wheelaghan, Orestes es
dc.creator Roselló Merino, Marta es
dc.creator Díez, Josefina es
dc.creator Maya Díaz, Celia María es
dc.creator López Serrano, Joaquín es
dc.creator Conejero, Salvador es
dc.date.accessioned 2018-09-21T10:58:48Z
dc.date.available 2018-09-21T10:58:48Z
dc.date.issued 2014
dc.identifier.citation Rivada Wheelaghan, O., Roselló Merino, M., Díez, J., Maya Díaz, C.M., López Serrano, J. y Conejero, S. (2014). Formation of C−X Bonds Through Stable Low-Electron Count Cationic Pt(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes. Organometallics, 33 (21), 5944-5947.
dc.identifier.issn 0276-7333 (impreso) es
dc.identifier.issn 1520-6041 (electrónico) es
dc.identifier.uri https://hdl.handle.net/11441/78704
dc.description.abstract Cationic five-coordinate Pt(IV) alkyl complexes stabilized by bulky N-heterocyclic carbenes have been isolated and fully characterized. Related species have been postulated as key intermediates in carbon–heteroatom coupling reactions and most particularly in Shilov-type chemistry. The alkyl groups exhibit a pronounced electrophilic character and can undergo nucleophilic addition of pyridine, bromide, or iodide to form new carbon–heteroatom bonds. Nevertheless, direct reductive coupling to form C–X bonds can be operative in the absence of an external nucleophile source. es
dc.description.sponsorship Ministerio de Ciencia, Innovación y Universidades CTQ2013-45011 es
dc.description.sponsorship Junta de Andalucía FQM-2126 es
dc.format application/pdf es
dc.language.iso eng es
dc.publisher American Chemical Society es
dc.relation.ispartof Organometallics, 33 (21), 5944-5947.
dc.rights Attribution-NonCommercial-NoDerivatives 4.0 Internacional *
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/4.0/ *
dc.title Formation of C−X Bonds Through Stable Low-Electron Count Cationic Pt(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes es
dc.type info:eu-repo/semantics/article es
dc.type.version info:eu-repo/semantics/acceptedVersion es
dc.rights.accessrights info:eu-repo/semantics/openAccess es
dc.contributor.affiliation Universidad de Sevilla. Departamento de Química Inorgánica es
dc.relation.projectID CTQ2013-45011 es
dc.relation.projectID FQM-2126 es
dc.relation.publisherversion http://dx.doi.org/10.1021/om500881k es
dc.identifier.doi 10.1021/om500881k es
idus.format.extent 5 es
dc.journaltitle Organometallics es
dc.publication.volumen 33 es
dc.publication.issue 21 es
dc.publication.initialPage 5944 es
dc.publication.endPage 5947 es
dc.contributor.funder Ministerio de Ciencia, Innovación y Universidades (MICINN). España
dc.contributor.funder Junta de Andalucía
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