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Mechanism of Alkyl Migration in Diorganomagnesium 2,6-Bis(imino)pyridine Complexes: Formation of Grignard-Type Complexes with Square-Planar Mg(II) Centers

 

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Opened Access Mechanism of Alkyl Migration in Diorganomagnesium 2,6-Bis(imino)pyridine Complexes: Formation of Grignard-Type Complexes with Square-Planar Mg(II) Centers
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Author: Sandoval, John J.
Palma, Pilar
Álvarez González, Eleuterio
Cámpora, Juan
Rodríguez Delgado, Antonio
Date: 2016
Published in: Organometallics, 35 (18), 3197-3204.
Document type: Article
Abstract: Dialkylmagnesium compounds [MgR2L2] (R = n-Bu, L = none or R = Bn, L = THF) react with 2,6-bis(imino)pyridines (BIP) to afford different types of Mg(II) alkyl complexes, depending on the nature of R. For R = n-Bu, thermally stable products resulting...
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Cite: Sandoval, J.J., Palma, P., Álvarez González, E., Cámpora, J. y Rodríguez Delgado, A. (2016). Mechanism of Alkyl Migration in Diorganomagnesium 2,6-Bis(imino)pyridine Complexes: Formation of Grignard-Type Complexes with Square-Planar Mg(II) Centers. Organometallics, 35 (18), 3197-3204.
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URI: https://hdl.handle.net/11441/77232

DOI: 10.1021/acs.organomet.6b00528

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