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Broad Scope Synthesis of Ester Precursors of Nonfunctionalized Chiral Alcohols Based on the Asymmetric Hydrogenation of α,β-Dialkyl-, α,β-Diaryl-, and α-Alkyl-β-aryl-vinyl Esters

 

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Opened Access Broad Scope Synthesis of Ester Precursors of Nonfunctionalized Chiral Alcohols Based on the Asymmetric Hydrogenation of α,β-Dialkyl-, α,β-Diaryl-, and α-Alkyl-β-aryl-vinyl Esters
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Author: León, Felix
González-Liste, Pedro J.
García-Garrido, Sergio E.
Arribas, Inmaculada
Rubio, Miguel
Cadierno, Victorio
Pizzano, Antonio
Date: 2017
Published in: Journal of Organic Chemistry, 82 (11), 5852-5867.
Document type: Article
Abstract: The catalytic asymmetric hydrogenation of trisubstituted enol esters using Rh catalysts bearing chiral phosphine-phosphite ligands (P-OP) has been studied. Substrates covered comprise α,β-dialkyl, α-alkyl-β-aryl, and α,β-diarylvinyl esters, the corr...
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Cite: León, F., González-Liste, P.J., García-Garrido, S.E., Arribas, I., Rubio, M., Cadierno, V. y Pizzano, A. (2017). Broad Scope Synthesis of Ester Precursors of Nonfunctionalized Chiral Alcohols Based on the Asymmetric Hydrogenation of α,β-Dialkyl-, α,β-Diaryl-, and α-Alkyl-β-aryl-vinyl Esters. Journal of Organic Chemistry, 82 (11), 5852-5867.
Size: 1.400Mb
Format: PDF

URI: https://hdl.handle.net/11441/75102

DOI: 10.1021/acs.joc.7b00710

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