Mostrar el registro sencillo del ítem
Artículo
Ligand Rearrangement and Hemilability in R hodium(I) and Iridium(I) Complexes Bearing Terphenyl Phosphines
dc.creator | Moreno Díaz, Juan José | es |
dc.creator | Fernández Espada, María | es |
dc.creator | Krüger, Eric | es |
dc.creator | López Serrano, Joaquín | es |
dc.creator | Campos, Jesús | es |
dc.creator | Carmona Guzmán, Ernesto | es |
dc.date.accessioned | 2018-04-13T12:06:50Z | |
dc.date.available | 2018-04-13T12:06:50Z | |
dc.date.issued | 2018 | |
dc.identifier.citation | Moreno Díaz, J.J., Fernández Espada, M., Krüger, E., López Serrano, J., Campos, J. y Carmona Guzmán, E. (2018). Ligand Rearrangement and Hemilability in R hodium(I) and Iridium(I) Complexes Bearing Terphenyl Phosphines. European Journal of Inorganic Chemistry | |
dc.identifier.issn | 1099-0682 | es |
dc.identifier.uri | https://hdl.handle.net/11441/72844 | |
dc.description.abstract | We describe the synthesis of a series of cationic rhodium(I) and iridium(I) compounds stabilized by sterically demanding phosphines that contain a terphenyl substituent, PMe 2 Ar’ (Ar’ = 2,6-diarylphenyl radical). Salt metathesis of metal precursors [MCl(COD)(PMe 2 Ar’)] (M = Rh, Ir; COD = cyclooctadiene) with NaBAr F (BAr F = B(3,5-C 6 H 3 (CF 3 ) 2 ) 4 ) results in a series of cationic complexes in which the loss of the chloride ligand is compensated by the appearance of relatively weak π-interactions with one of the flanking aryl rings of the terphenyl substituent. The same experiments carried out with carbonyl compounds [MCl(CO) 2 (PMe 2 Ar’)] led to the corresponding cationic carbonyl complexes, whose CO-induced rearrangement reactivity has been investigated, both experimentally and computationally. The differences in reactivity between rhodium and iridium complexes, and as a result of varying the sterics of terphenyl phosphines are discussed | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Wiley | es |
dc.relation.ispartof | European Journal of Inorganic Chemistry | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Ligand Rearrangement and Hemilability in R hodium(I) and Iridium(I) Complexes Bearing Terphenyl Phosphines | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/submittedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.publisherversion | https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.201800169 | es |
dc.identifier.doi | 10.1002/ejic.201800169 | es |
dc.journaltitle | European Journal of Inorganic Chemistry | es |
Ficheros | Tamaño | Formato | Ver | Descripción |
---|---|---|---|---|
EurJIC Preprint-1.pdf | 911.7Kb | [PDF] | Ver/ | |