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Investigations on the Coupling of Ethylene and Alkynes in Tp Me2 Ir Compounds: Water as an Effective Trapping Agent

 

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Opened Access Investigations on the Coupling of Ethylene and Alkynes in Tp Me2 Ir Compounds: Water as an Effective Trapping Agent
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Author: Álvarez González, Eleuterio
Paneque Sosa, Margarita
Martín Posadas, Cristina Isabel
López Poveda, Manuel
Rendón Márquez, Nuria
Mereiter, Kurt
Department: Universidad de Sevilla. Departamento de Química Inorgánica
Date: 2007
Document type: Article
Abstract: The reaction of the bis(ethylene) complex [TpMe2Ir(C2H4)2] (1) (TpMe: hydrotris(3,5-dimethylpyrazolyl)borate) with two equivalents of dimethyl acetylenedicarboxylate (DMAD) in CH2Cl2 at 25 °C gives the hydride–alkenyl species [TpMe2IrH{C(R)=C(R)C(R)...
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URI: https://hdl.handle.net/11441/70956

DOI: 10.1002/chem.200601500

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