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Protonolysis of Fe-C bonds of a diiminopyridineiron(II) dialkyl complex by acids of different strengths: Influence of monoanionic ligands on the spectroscopic properties of diiminopyiridine-FeY2 complexes

dc.creatorCartes Domínguez, María Ángeleses
dc.creatorPalma Ramírez, María del Pilares
dc.creatorSandoval Valencia, John Jairoes
dc.creatorCámpora Pérez, Juanes
dc.creatorÁlvarez González, Eleuterioes
dc.date.accessioned2018-01-22T15:11:40Z
dc.date.available2018-01-22T15:11:40Z
dc.date.issued2014
dc.identifier.citationCartes Domínguez, M.Á., Palma Ramírez, M.d. ., Sandoval Valencia, J.J., Cámpora Pérez, J. y Álvarez González, E. (2014). Protonolysis of Fe-C bonds of a diiminopyridineiron(II) dialkyl complex by acids of different strengths: Influence of monoanionic ligands on the spectroscopic properties of diiminopyiridine-FeY2 complexes. Inorganica Chimica Acta, 412, 73-78.
dc.identifier.issn0020-1693es
dc.identifier.urihttps://hdl.handle.net/11441/69325
dc.description.abstractThe reaction of the dialkyliron complex [Fe(CH2SiMe 3)2(MesBIP)] (MesBIP = 2,6-bis((N-mesityl)acetimidoyl)pyridine) with protic acids (HY) of different strengths (Y = C6F5O, CF3CO2, Cl, CF3SO3) invariably leads to the cleavage of both Fe-C bonds, independent of the Fe/HY ratio used (either 1:2 or 1:1), affording the corresponding complexes [FeY2(MesBIP)]. Relevant spectroscopic features of these compounds, such as paramagnetic 1H NMR shifts and UV-Vis absorption bands, exhibit a marked dependence on the nature of Yes
dc.description.sponsorshipGobierno de España CTQ2012-30962es
dc.description.sponsorshipJunta de Andalucía FQM5074es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherElsevieres
dc.relation.ispartofInorganica Chimica Acta, 412, 73-78.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectIrones
dc.subjectAlkyl complexeses
dc.subjectOlefin polymerizationes
dc.subject2,6-bisiminopyridine ligandses
dc.titleProtonolysis of Fe-C bonds of a diiminopyridineiron(II) dialkyl complex by acids of different strengths: Influence of monoanionic ligands on the spectroscopic properties of diiminopyiridine-FeY2 complexeses
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/submittedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.projectIDCTQ2012-30962es
dc.relation.projectIDFQM5074es
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.ica.2013.11.028es
dc.identifier.doi10.1016/j.ica.2013.11.028es
idus.format.extent12 p.es
dc.journaltitleInorganica Chimica Actaes
dc.publication.volumen412es
dc.publication.initialPage73es
dc.publication.endPage78es
dc.contributor.funderGobierno de España
dc.contributor.funderJunta de Andalucía

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