dc.creator | Cartes Domínguez, María Ángeles | es |
dc.creator | Palma Ramírez, María del Pilar | es |
dc.creator | Sandoval Valencia, John Jairo | es |
dc.creator | Cámpora Pérez, Juan | es |
dc.creator | Álvarez González, Eleuterio | es |
dc.date.accessioned | 2018-01-22T15:11:40Z | |
dc.date.available | 2018-01-22T15:11:40Z | |
dc.date.issued | 2014 | |
dc.identifier.citation | Cartes Domínguez, M.Á., Palma Ramírez, M.d. ., Sandoval Valencia, J.J., Cámpora Pérez, J. y Álvarez González, E. (2014). Protonolysis of Fe-C bonds of a diiminopyridineiron(II) dialkyl complex by acids of different strengths: Influence of monoanionic ligands on the spectroscopic properties of diiminopyiridine-FeY2 complexes. Inorganica Chimica Acta, 412, 73-78. | |
dc.identifier.issn | 0020-1693 | es |
dc.identifier.uri | https://hdl.handle.net/11441/69325 | |
dc.description.abstract | The reaction of the dialkyliron complex [Fe(CH2SiMe 3)2(MesBIP)] (MesBIP = 2,6-bis((N-mesityl)acetimidoyl)pyridine) with protic acids (HY) of different strengths (Y = C6F5O, CF3CO2, Cl, CF3SO3) invariably leads to the cleavage of both Fe-C bonds, independent of the Fe/HY ratio used (either 1:2 or 1:1), affording the corresponding complexes [FeY2(MesBIP)]. Relevant spectroscopic features of these compounds, such as paramagnetic 1H NMR shifts and UV-Vis absorption bands, exhibit a marked dependence on the nature of Y | es |
dc.description.sponsorship | Gobierno de España CTQ2012-30962 | es |
dc.description.sponsorship | Junta de Andalucía FQM5074 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Elsevier | es |
dc.relation.ispartof | Inorganica Chimica Acta, 412, 73-78. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Iron | es |
dc.subject | Alkyl complexes | es |
dc.subject | Olefin polymerization | es |
dc.subject | 2,6-bisiminopyridine ligands | es |
dc.title | Protonolysis of Fe-C bonds of a diiminopyridineiron(II) dialkyl complex by acids of different strengths: Influence of monoanionic ligands on the spectroscopic properties of diiminopyiridine-FeY2 complexes | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/submittedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.relation.projectID | CTQ2012-30962 | es |
dc.relation.projectID | FQM5074 | es |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.ica.2013.11.028 | es |
dc.identifier.doi | 10.1016/j.ica.2013.11.028 | es |
idus.format.extent | 12 p. | es |
dc.journaltitle | Inorganica Chimica Acta | es |
dc.publication.volumen | 412 | es |
dc.publication.initialPage | 73 | es |
dc.publication.endPage | 78 | es |
dc.contributor.funder | Gobierno de España | |
dc.contributor.funder | Junta de Andalucía | |