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Functional group directed C-H borylation


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Author: Ros Lao, Abel
Fernández Fernández, Rosario Fátima
Lassaletta Simón, José María
Department: Universidad de Sevilla. Departamento de Química orgánica
Date: 2014
Published in: Chemical Society Reviews, 43, 3229-3243.
Document type: Article
Abstract: The direct borylation of hydrocarbons via C-H activation has reached an impressive level of sophistication and efficiency, emerging as a fundamental tool in synthesis because of the versatility offered by organoboron compounds. As a remarkable particularity, the catalytic systems originally developed for these reactions are relatively insensitive to directing effects, and the regioselectivity of the borylations is typically governed by steric factors. Likely stimulated by the great synthetic potential of the expected functionalised organoboranes, however, many groups have recently focused on the development of complementary strategies for directed, site-selective borylation reactions where a directing group controls the course of the reaction. In this tutorial review, the different strategies and findings related to the development of these directed borylation reactions via C(sp2)-H or C(sp3)-H activation will be summarized and discussed. © 2014 the Partner Organisations.
Cite: Ros Lao, A., Fernández Fernández, R. y Lassaletta Simón, J.M. (2014). Functional group directed C-H borylation. Chemical Society Reviews, 43, 3229-3243.
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DOI: 10.1039/c3cs60418g

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