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Direct evidence for a coordination-insertion mechanism of ethylene oligomerization catalysed by neutral 2,6-bisiminopyridine iron monoalkyl complexes

dc.creatorCartes Domínguez, María Ángeleses
dc.creatorRodríguez Delgado, Antonioes
dc.creatorPalma Ramírez, María del Pilares
dc.creatorSánchez Fernández, Luises
dc.creatorCámpora Pérez, Juanes
dc.date.accessioned2018-01-03T15:11:57Z
dc.date.available2018-01-03T15:11:57Z
dc.date.issued2014
dc.identifier.citationCartes Domínguez, M.Á., Rodríguez Delgado, A., Palma Ramírez, M.d.P., Sánchez Fernández, L. y Cámpora Pérez, J. (2014). Direct evidence for a coordination-insertion mechanism of ethylene oligomerization catalysed by neutral 2,6-bisiminopyridine iron monoalkyl complexes. Catalysis Science and Technology, 4, 2504-2507.
dc.identifier.issn2044-4761es
dc.identifier.urihttp://hdl.handle.net/11441/68196
dc.description.abstract1H NMR studies on ethylene oligomerization catalysed by the neutral monoalkyl complex [Fe(Me)(iPrBIP)] allow direct observation of alkyl iron intermediates as well as reversible ethylene coordination to the metal center, providing for the first time experimental evidence for a coordination-insertion mechanism of iron-catalysed ethylene upgrade reactions.es
dc.description.sponsorshipMinisterio de Economía y Competitividad CTQ2012-30962es
dc.description.sponsorshipJunta de Andalucía FQM5074es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.relation.ispartofCatalysis Science and Technology, 4, 2504-2507.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleDirect evidence for a coordination-insertion mechanism of ethylene oligomerization catalysed by neutral 2,6-bisiminopyridine iron monoalkyl complexeses
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Inorgánicaes
dc.relation.projectIDCTQ2012-30962es
dc.relation.projectIDFQM5074es
dc.relation.publisherversionhttp://dx.doi.org/10.1039/c4cy00612ges
dc.identifier.doi10.1039/c4cy00612ges
idus.format.extent4 p.es
dc.journaltitleCatalysis Science and Technologyes
dc.publication.volumen4es
dc.publication.initialPage2504es
dc.publication.endPage2507es
dc.contributor.funderMinisterio de Economía y Competitividad (MINECO). España
dc.contributor.funderJunta de Andalucía

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