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A simple, general route to 2-pyridylidene transition metal complexes

 

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dc.creator Roselló Merino, Marta es
dc.creator Díez, Josefina es
dc.creator Conejero Iglesias, Salvador es
dc.date.accessioned 2017-12-29T09:28:06Z
dc.date.available 2017-12-29T09:28:06Z
dc.date.issued 2010-11-04
dc.identifier.issn 1359-7345 (impreso) es
dc.identifier.uri http://hdl.handle.net/11441/68072
dc.description.abstract Pyridinium 2-carboxylates decompose thermally in the presence of a variety of late transition metal precursors to yield the corresponding 2-pyridylidene-like complexes. The mild reaction conditions and structural diversity that can be generated in the heterocyclic ring make this method an attractive alternative for the synthesis of 2-pyridylidene complexes. IR spectra of the Ir(I) carbonyl compounds [IrCl(NHC)(CO)2] indicate that these N-heterocyclic carbene ligands are among the strongest σ-electron donors. es
dc.description.sponsorship Junta de Andalucía FQM-3151 es
dc.description.sponsorship Ministerio de Ciencia e Innovación CTQ2007-62814, CONSOLIDER-INGENIO 2010 CSD2007-00006 es
dc.format application/pdf es
dc.language.iso eng es
dc.publisher Royal Society of Chemistry (Great Britain) es
dc.rights Attribution-NonCommercial-NoDerivatives 4.0 Internacional *
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/4.0/ *
dc.subject N-heterocyclic carbenes es
dc.subject Nitrogen es
dc.subject C-H activation es
dc.subject Pyridinium salts es
dc.subject NMR spectroscopy es
dc.subject X-ray crystallography es
dc.subject Electron donors es
dc.title A simple, general route to 2-pyridylidene transition metal complexes es
dc.type info:eu-repo/semantics/article es
dc.type.version info:eu-repo/semantics/acceptedVersion es
dc.rights.accessrights info:eu-repo/semantics/openAccess es
dc.contributor.affiliation Universidad de Sevilla. Departamento de Química Inorgánica es
dc.relation.projectID FQM-3151 es
dc.relation.projectID CTQ2007-62814 es
dc.relation.projectID CSD2007-00006 es
dc.relation.publisherversion http://dx.doi.org/10.1039/C0CC03935G es
dc.identifier.doi 10.1039/C0CC03935G es
idus.format.extent 3 p. es
dc.journaltitle Chemical Communications es
dc.publication.volumen 46 es
dc.publication.issue 48 es
dc.publication.initialPage 9247 es
dc.publication.endPage 9249 es
dc.contributor.funder Junta de Andalucía
dc.contributor.funder Ministerio de Ciencia e Innovación (MICIN). España
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