dc.creator | López Santos, Laura | es |
dc.creator | Paneque Sosa, Margarita | es |
dc.creator | Mereiter, Kurt | es |
dc.date.accessioned | 2017-04-11T12:05:17Z | |
dc.date.available | 2017-04-11T12:05:17Z | |
dc.date.issued | 2013 | |
dc.identifier.citation | López Santos, L., Paneque Sosa, M. y Mereiter, K. (2013). Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl) hydroborato]iridium(III) chloroform monosolvate. Acta Crystallographica Section E: Structure Reports Online, 69 (4), 224-225. | |
dc.identifier.issn | 1600-5368 | es |
dc.identifier.uri | http://hdl.handle.net/11441/57482 | |
dc.description.abstract | In the title compound, [Ir(C15H22BN6)(C8H7O)Cl]·CHCl3, the Ir atom is formally trivalent and is coordinated in a slightly distorted octahedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir Ccarbene bond is strong and short and exerts a notable effect on the trans-Ir—N bond, which is about 0.10 A˚ longer than the two other Ir—N
bonds. The chloroform solvent molecule is anchored via a weak C—H·· ·Cl hydrogen bond to the Cl atom of the Ir complex molecule. In the crystal, the constituents adopt a layer-like arrangement parallel to (010) and are held together by weak intermolecular C—H·· ·Cl hydrogen bonds, as well as
weak Cl·· ·Cl [3.498 (2) A˚ ] and Cl·· ·JT [3.360 (4) A˚ ] inter-
actions. A weak intramolecular C—H·· ·O hydrogen bond is also observed | es |
dc.description.sponsorship | FEDER CTQ2010–17476 | es |
dc.description.sponsorship | Consolider-Ingenio 2010 CSD2007–00006 | es |
dc.description.sponsorship | Junta de Andalucía FQM-119 P09-FQM-4832 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | International Union of Crystallography | es |
dc.relation.ispartof | Acta Crystallographica Section E: Structure Reports Online, 69 (4), 224-225. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl) hydroborato]iridium(III) chloroform monosolvate | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | CTQ2010–17476 | es |
dc.relation.projectID | CSD2007–00006 | es |
dc.relation.projectID | FQM-119 | es |
dc.relation.projectID | P09-FQM-4832 | es |
dc.relation.publisherversion | 10.1107/S1600536813007344 | es |
idus.format.extent | 14 p. | es |
dc.journaltitle | Acta Crystallographica Section E: Structure Reports Online | es |
dc.publication.volumen | 69 | es |
dc.publication.issue | 4 | es |
dc.publication.initialPage | 224 | es |
dc.publication.endPage | 225 | es |