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Síntesis del 2-amino-2-desoxi-d-glicero-d-ido-heptononitrilo y de algunos de sus derivados

 

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Opened Access Síntesis del 2-amino-2-desoxi-d-glicero-d-ido-heptononitrilo y de algunos de sus derivados
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Author: Galbis Pérez, Juan Antonio
Gómez Guillén, M.
Jiménez Requejo, J. L.
Department: Universidad de Sevilla. Departamento de Química Orgánica y Farmacéutica
Date: 1979
Published in: Anales de química, 75, 426-427.
Document type: Article
Abstract: Treatment of a suspension of !l-0-glucopyranosylamine in pyridine with dry hydro­ gen cyanide affords, at room temperature. in good yield, 2-amino-2 -deoxy-O·g/ycero·O·ido· heptononitrile (1). The structure of 1 is assigned on the basis of spectroscopic and chemical methods. Benzoylation of 1 gives the hexabenzoy l derivative 11. and treatment of 1 with benzyl chlorocarbo nate, yields the 2-benzyloxycarbonylamino-2 -deoxy- D-g/ycero-D-ido -heptononitrile (111).
Cite: Galbis Pérez, J.A., Gómez Guillén, M. y Jiménez Requejo, J.L. (1979). Síntesis del 2-amino-2-desoxi-d-glicero-d-ido-heptononitrilo y de algunos de sus derivados. Anales de química, 75, 426-427.
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URI: http://hdl.handle.net/11441/46570

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