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Absolute Configuration of Falcarinol (9Z-heptadeca-1,9-diene-4,6- diyn-3-ol) from Pastinaca sativa

dc.creatorCorell González, Mireiaes
dc.creatorSheehyb, Eimileees
dc.creatorEvans, Paules
dc.creatorBrunton, Nigeles
dc.creatorValverde, Juanes
dc.date.accessioned2020-04-23T17:08:07Z
dc.date.available2020-04-23T17:08:07Z
dc.date.issued2013
dc.identifier.citationCorell González, M., Sheehyb, E., Evans, P., Brunton, N. y Valverde, J. (2013). Absolute Configuration of Falcarinol (9Z-heptadeca-1,9-diene-4,6- diyn-3-ol) from Pastinaca sativa. Natural Product Communications, 2013 (8) (2013 (8)), 1123 p.-1126 p..
dc.identifier.issn1934-578Xes
dc.identifier.issne 1555-9475es
dc.identifier.urihttps://hdl.handle.net/11441/95682
dc.description.abstractFalcarinol (9Z-heptadeca-1,9-diene-4,6-diyn-3-ol; 1) is a polyacetylene commonly found in several plant families. The absolute configuration of naturally occurring 1 is not clear and contradictory results have been reported in the literature. Determination of the absolute configuration of 1 from Pastinaca sativa L. was carried out. Isolation of 95% pure 1 was performed via successive fractionation and preparative-HPLC. A racemic mixture comprised of 3R-1 and 3S-1 was synthesized in order to confirm the absolute configuration of the isolated natural product using chiral HPLC. Based on a combination of chiral HPLC and specific rotation, 1 present in P. sativa was found to have a 3R absolute configuration (i.e. (3R, 9Z)-heptadeca-1,9-diene-4,6-diyn-3-ol).es
dc.formatapplication/pdfes
dc.format.extent4 p.es
dc.language.isoenges
dc.publisherNatural Product Communicationses
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectFalcarinol (9Z-heptadeca-1,9-diene-4,6-diyn-3-ol)es
dc.subjectAbsolute configurationes
dc.subjectPastinaca sativa Les
dc.subjectChiral chromatographyes
dc.titleAbsolute Configuration of Falcarinol (9Z-heptadeca-1,9-diene-4,6- diyn-3-ol) from Pastinaca sativaes
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Ciencias Agroforestaleses
dc.relation.publisherversionhttps://journals.sagepub.com/doi/pdf/10.1177/1934578X1300800824es
dc.identifier.doi10.1177/1934578X1300800824es
dc.contributor.groupUniversidad de Sevilla. AGR188: Agronomíaes
dc.journaltitleNatural Product Communicationses
dc.publication.volumen2013 (8)es
dc.publication.issue2013 (8)es
dc.publication.initialPage1123 p.es
dc.publication.endPage1126 p.es
dc.identifier.sisius16685es

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