dc.creator | Galindo del Pozo, Agustín | es |
dc.creator | Carmona Durán, Ernesto | es |
dc.creator | Pérez, Pedro J. | es |
dc.creator | Álvarez, María | es |
dc.date.accessioned | 2020-03-05T11:50:18Z | |
dc.date.available | 2020-03-05T11:50:18Z | |
dc.date.issued | 2019 | |
dc.identifier.citation | Galindo del Pozo, A., Carmona Durán, E., Pérez, P.J. y Álvarez, M. (2019). Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands. Chemical Science, 10, 8541-8546. | |
dc.identifier.issn | 2041-6539 | es |
dc.identifier.uri | https://hdl.handle.net/11441/93916 | |
dc.description.abstract | The first examples of stable metal complexes with coordinated ethylene and carbon dioxide ligands are reported. Reaction of tris(ethylene) complexes mer-M(C2H4)3(PNP) (M = Mo and W; PNP = 2,6-bis(diphenylphosphinomethyl)pyridine) with CO2 yields the corresponding, mixed cis-M(C2H4)2(CO2)(PNP) derivatives. X-ray studies reveal six-coordinate structures exhibiting η2-ethylene and κ2-C,O carbon dioxide coordination. Remarkably, the formation of the molybdenum CO2 adduct occurs also in the solid state at room temperature, under 4 bar of CO2, in a nearly quantitative manner. | es |
dc.description.sponsorship | España MINECO CTQ2017-82893-C2- 1-R and CTQ2017-82893-C2-2-R | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry | es |
dc.relation.ispartof | Chemical Science, 10, 8541-8546. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | CTQ2017-82893-C2-2-R | es |
dc.relation.projectID | CTQ2017-82893-C2- 1-R | es |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c9sc03225h | es |
dc.identifier.doi | 10.1039/c9sc03225h | es |
idus.format.extent | 6 p. | es |
dc.journaltitle | Chemical Science | es |
dc.publication.volumen | 10 | es |
dc.publication.initialPage | 8541 | es |
dc.publication.endPage | 8546 | es |