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Reactivity of a gold(i)/platinum(0) frustrated Lewis pair with germanium and tin dihalides

dc.creatorHidalgo, Nereidaes
dc.creatorBajo Velázquez, Soniaes
dc.creatorMoreno Díaz, Juan Josées
dc.creatorNavarro Gilabert, Carloses
dc.creatorMercado, Brandon Q.es
dc.creatorCampos Manzano, Jesúses
dc.date.accessioned2019-09-17T09:40:31Z
dc.date.available2019-09-17T09:40:31Z
dc.date.issued2019
dc.identifier.citationHidalgo, N., Bajo Velázquez, S., Moreno Díaz, J.J., Navarro Gilabert, C., Mercado, B.Q. y Campos Manzano, J. (2019). Reactivity of a gold(i)/platinum(0) frustrated Lewis pair with germanium and tin dihalides. Dalton Transactions, 48 (25), 9127-9138.
dc.identifier.issn1477-9226es
dc.identifier.issn1477-9234es
dc.identifier.urihttps://hdl.handle.net/11441/89170
dc.description.abstractThe reactivity of germanium and tin dichlorides with a transition metal-only frustrated Lewis pair based on Au(i) and Pt(0) compounds bearing bulky phosphine ligands is described in this work. We have examined both the reactivity of tetrylene dihalides towards the individual components of the metallic pair, as well as under metal/metal cooperative conditions. These studies allowed us to isolate several uncommon homo- and heterometallic structures. Computational methods have been employed to investigate the bonding scheme of one of these highly-reduced metallic aggregates. In addition, we have developed a tin-promoted strategy to access heteroleptic diphosphine platinum(0) compounds.es
dc.description.sponsorshipEuropean Research Council 756575es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.relation.ispartofDalton Transactions, 48 (25), 9127-9138.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectGermaniumes
dc.subjectLigandses
dc.titleReactivity of a gold(i)/platinum(0) frustrated Lewis pair with germanium and tin dihalideses
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationInstituto de Investigaciones Químicas (IIQ) – CIC Cartujaes
dc.relation.projectID756575es
dc.relation.publisherversionhttps://doi.org/10.1039/c9dt00702des
dc.identifier.doi10.1039/c9dt00702des
idus.format.extent12 p.es
dc.journaltitleDalton Transactionses
dc.publication.volumen48es
dc.publication.issue25es
dc.publication.initialPage9127es
dc.publication.endPage9138es

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