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dc.creatorCarmona Guzmán, Ernestoes
dc.creatorCámpora Pérez, Juanes
dc.creatorMuñoz, Miguel Ángeles
dc.creatorPaneque Sosa, Margaritaes
dc.creatorPoveda, Manuel L.es
dc.date.accessioned2019-09-10T08:33:05Z
dc.date.available2019-09-10T08:33:05Z
dc.date.issued1989
dc.identifier.citationCarmona Guzmán, E., Cámpora Pérez, J., Muñoz, M.Á., Paneque Sosa, M. y Poveda, M.L. (1989). Electron-rich metal complexes for C02 and CS2 incorporation. Pure and Applied Chemistry, 61 (10), 1701-1706.
dc.identifier.issn0033-4545es
dc.identifier.urihttps://hdl.handle.net/11441/89078
dc.description.abstractThe dihapto coordination of two molecules of carbon dioxide to a square-planar MoP2(P-P) fragment (P=monodentate-, P-P=bidentate phosphi- ne ligands) can occur in several ways giving rise to different conformers. Compounds of this type have been prepared and their spectroscopic proper- ties investigated by variable temperature 'H and 31P NMR studies. The for- mation of ethylene complexes related to Mo(C2H4)2(PMe3)4, 6, and the study of their reactivity towards carbon dioxide and carbon disulphide is also described. In particular, compound 6 induces a head-to-tail dimerization of carbon disulphide with formation of a Mo(II)-C$4 linkage, which, in the presence of carbon monoxide, undergoes a symmetric, oxidative rupture, which produces a Mo(0) complex and two molecules of carbon disulphide. The insertion reactions of carbon dioxide and other unsaturated molecules into the nickel-carbon bonds of the nickelacyclopentene complexes 9 have been investigated and different organic products isolated by means of simple or sequential insertion reactions.es
dc.description.sponsorshipMinisterio de Educación y Cienciaes
dc.description.sponsorshipAgencia Nacional de Evaluación y Prospectivaes
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherWalter de Gruyter GmbHes
dc.relation.ispartofPure and Applied Chemistry, 61 (10), 1701-1706.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleElectron-rich metal complexes for C02 and CS2 incorporationes
dc.typeinfo:eu-repo/semantics/articlees
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessrightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Inorgánicaes
dc.relation.publisherversionhttp://www.old.iupac.org/publications/pac/1989/pdf/6110x1701.pdfes
idus.format.extent7 p.es
dc.journaltitlePure and Applied Chemistryes
dc.publication.volumen61es
dc.publication.issue10es
dc.publication.initialPage1701es
dc.publication.endPage1706es
dc.identifier.sisius20535714es

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