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dc.creatorPérez Jiménez, Marinaes
dc.creatorCampos Manzano, Jesúses
dc.creatorLópez Serrano, Joaquínes
dc.creatorCarmona Guzmán, Ernestoes
dc.date.accessioned2019-08-16T08:12:26Z
dc.date.available2019-08-16T08:12:26Z
dc.date.issued2018
dc.identifier.citationPérez Jiménez, M., Campos Manzano, J., López Serrano, J. y Carmona Guzmán, E. (2018). Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions. Chemical Communications, 54, 9186-9189.
dc.identifier.issn1359-7345 (impreso)es
dc.identifier.issn1364-548X (electrónico)es
dc.identifier.urihttps://hdl.handle.net/11441/88395
dc.description.abstractComplex [Mo2(H)2{μ-HC(NDipp)2}2(THF)2], (1·THF), reacts with C2H4 and PhCH[double bond, length as m-dash]CH2 to afford hydrido-hydrocarbyl and bis(hydrocarbyl) derivatives of the Mo[quadruple bond, length as m-dash]Mo bond. Reversible migratory insertion and β-hydrogen elimination, as well as reductive elimination and other reactions, have been uncovered. PhC[triple bond, length as m-dash]CH behaves instead as a Brönsted–Lowry acid towards the strongly basic Mo–H bonds of 1·THF.es
dc.description.sponsorshipMinisterio de Economía y Competitividad CTQ2016-75193-Pes
dc.description.sponsorshipEuropean Research Council 756575es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.relation.ispartofChemical Communications, 54, 9186-9189.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleReactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactionses
dc.typeinfo:eu-repo/semantics/articlees
dc.type.versioninfo:eu-repo/semantics/submittedVersiones
dc.rights.accessrightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Inorgánicaes
dc.relation.projectIDCTQ2016-75193-Pes
dc.relation.projectID756575es
dc.relation.publisherversionhttp://dx.doi.org/10.1039/C8CC04945Aes
dc.identifier.doi10.1039/C8CC04945Aes
idus.format.extent4 p.es
dc.journaltitleChemical Communicationses
dc.publication.volumen54es
dc.publication.initialPage9186es
dc.publication.endPage9189es

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