| dc.creator | Pérez Jiménez, Marina | es |
| dc.creator | Campos Manzano, Jesús | es |
| dc.creator | López Serrano, Joaquín | es |
| dc.creator | Carmona Guzmán, Ernesto | es |
| dc.date.accessioned | 2019-08-16T08:12:26Z | |
| dc.date.available | 2019-08-16T08:12:26Z | |
| dc.date.issued | 2018 | |
| dc.identifier.citation | Pérez Jiménez, M., Campos Manzano, J., López Serrano, J. y Carmona Guzmán, E. (2018). Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions. Chemical Communications, 54, 9186-9189. | |
| dc.identifier.issn | 1359-7345 (impreso) | es |
| dc.identifier.issn | 1364-548X (electrónico) | es |
| dc.identifier.uri | https://hdl.handle.net/11441/88395 | |
| dc.description.abstract | Complex [Mo2(H)2{μ-HC(NDipp)2}2(THF)2], (1·THF), reacts with C2H4 and PhCH[double bond, length as m-dash]CH2 to afford hydrido-hydrocarbyl and bis(hydrocarbyl) derivatives of the Mo[quadruple bond, length as m-dash]Mo bond. Reversible migratory insertion and β-hydrogen elimination, as well as reductive elimination and other reactions, have been uncovered. PhC[triple bond, length as m-dash]CH behaves instead as a Brönsted–Lowry acid towards the strongly basic Mo–H bonds of 1·THF. | es |
| dc.description.sponsorship | Ministerio de Economía y Competitividad CTQ2016-75193-P | es |
| dc.description.sponsorship | European Research Council 756575 | es |
| dc.format | application/pdf | es |
| dc.language.iso | eng | es |
| dc.publisher | Royal Society of Chemistry | es |
| dc.relation.ispartof | Chemical Communications, 54, 9186-9189. | |
| dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
| dc.title | Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions | es |
| dc.type | info:eu-repo/semantics/article | es |
| dcterms.identifier | https://ror.org/03yxnpp24 | |
| dc.type.version | info:eu-repo/semantics/submittedVersion | es |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
| dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
| dc.relation.projectID | CTQ2016-75193-P | es |
| dc.relation.projectID | 756575 | es |
| dc.relation.publisherversion | http://dx.doi.org/10.1039/C8CC04945A | es |
| dc.identifier.doi | 10.1039/C8CC04945A | es |
| idus.format.extent | 4 p. | es |
| dc.journaltitle | Chemical Communications | es |
| dc.publication.volumen | 54 | es |
| dc.publication.initialPage | 9186 | es |
| dc.publication.endPage | 9189 | es |
Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions
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