dc.creator | Arzac, G. M. | es |
dc.creator | Montes, O. | es |
dc.creator | Fernández Camacho, Asunción | es |
dc.date.accessioned | 2018-11-15T15:31:05Z | |
dc.date.available | 2018-11-15T15:31:05Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | Arzar de Calvo, G.M., Montes, O. y Fernández Camacho, M.A. (2016). Pt-impregnated catalysts on powdery SiC and other commercial supports for the combustion of hydrogen under oxidant conditions. Applied Catalysis B - Environmental, 201, 391-399. | |
dc.identifier.issn | 0926-3373 | es |
dc.identifier.uri | https://hdl.handle.net/11441/80246 | |
dc.description.abstract | We report the study of the catalytic hydrogen combustion over Pt-impregnated powdery silicon carbide (SiC) using H2PtCl6 as precursor. The reaction was conducted in excess of oxygen. β-SiC was selected for the study because of its thermal conductivity, mechanical properties, chemical inertness and surface area. The obtained Pt particles over SiC were medium size (average particle diameter of 5 nm for 0.5 wt% Pt). The activity of the Pt-impregnated catalyst over SiC was compared to those obtained in oxidized form over TiO2 and Al2O3 commercial supports (Pt particles very small in size, average particle diameter of 1 nm for 0.5 wt% Pt in both cases). The case of a SiO2 support was also discussed. Those Pt/SiC particles were the most active because of their higher contribution of surface Pt0, indicating that partially oxidized surfaces have better activity than those totally oxidized in these conditions. SiC was modified with an acid treatment and thus bigger (average particle diameter of 7 nm for 0.5 wt% Pt) and more active Pt particles were obtained. Durability of the SiC and TiO2 supported catalysts was tested upon 5 cycles and both have shown to be durable and even more active than initially. Exposure to the oxidative reaction mixture activates the catalysts and the effect is more pronounced for the completely oxidized particles. This is due to the surface oxygen chemisorption which activates catalystś surface. | es |
dc.description.sponsorship | Junta de Andalucía PE2012-TEP862 | es |
dc.description.sponsorship | Ministerio de Economía y Competitividad CTQ2012-32519, CTQ2015-65918-R | es |
dc.description.sponsorship | Consejo Superior de Investigaciones Científicas PIE-201460E018 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Elsevier | es |
dc.relation.ispartof | Applied Catalysis B - Environmental, 201, 391-399. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Hydrogen | es |
dc.subject | Catalytic combustion | es |
dc.subject | Pt-impregnated catalysts | es |
dc.subject | Powdery SiC | es |
dc.title | Pt-impregnated catalysts on powdery SiC and other commercial supports for the combustion of hydrogen under oxidant conditions | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Instituto de Ciencia de Materiales de Sevilla (ICMS) – CIC Cartuja | es |
dc.relation.projectID | PE2012-TEP862 | es |
dc.relation.projectID | CTQ2012-32519 | es |
dc.relation.projectID | CTQ2015-65918-R | es |
dc.relation.projectID | PIE-201460E018 | es |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.apcatb.2016.08.042 | es |
dc.identifier.doi | 10.1016/j.apcatb.2016.08.042 | es |
idus.format.extent | 37 p. | es |
dc.journaltitle | Applied Catalysis B - Environmental | es |
dc.publication.volumen | 201 | es |
dc.publication.initialPage | 391 | es |
dc.publication.endPage | 399 | es |