dc.creator | Campos Manzano, Jesús | es |
dc.creator | Rubio Moreno, Miguel | es |
dc.creator | Esqueda Oliva, Ana Cristina | es |
dc.creator | Carmona Guzmán, Ernesto | es |
dc.date.accessioned | 2018-10-10T14:49:39Z | |
dc.date.available | 2018-10-10T14:49:39Z | |
dc.date.issued | 2012 | |
dc.identifier.citation | Campos Manzano, J., Rubio Moreno, M., Esqueda Oliva, A.C. y Carmona Guzmán, E. (2012). Large-scale preparation and labelling reactions of deuterated silanes. Journal of Labelled Compounds and Radiopharmaceuticals, 55, 29-38. | |
dc.identifier.issn | 0362-4803 (impreso) | es |
dc.identifier.issn | 1099-1344 (electrónico) | es |
dc.identifier.uri | https://hdl.handle.net/11441/79316 | |
dc.description.abstract | A catalytic synthesis of deuterated silanes SiEt3D, SiMe2PhD and SiPh2D2 is reported that allows their facile generation in a 3–4 g scale, utilizing D2 (0.5 bar) as the hydrogen isotope source and low catalyst loadings (0.01 mol%). The catalyst precursor is the rhodium (III) complex 1, which contains a (η5‐C5Me5)Rh cation stabilized by coordination to a cyclometallated phoshine PMeXyl2 (Xyl = 2,6‐C6H3Me2). The same complex is also an active catalyst for the hydrosilylation of the CO and C≡N bonds of various ketones, aldehydes and α,β‐unsaturated nitriles. Hence, combination of these two properties permits development of a simple and proficient one‐flask, two‐step procedure for the deuterosilylation of these substrates. | es |
dc.description.sponsorship | Ministerio de Ciencia y Tecnología CTQ2010‐17476, Consolider‐Ingenio 2010 CSD2007‐00006 | es |
dc.description.sponsorship | Junta de Andalucía FQM‐119, P09‐FQM‐4832 | es |
dc.description.sponsorship | Ministerio de Educación AP20080256 | es |
dc.description.sponsorship | CONACYT (Mexico) 22934 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | John Wiley & Sons | es |
dc.relation.ispartof | Journal of Labelled Compounds and Radiopharmaceuticals, 55, 29-38. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Deuterium | es |
dc.subject | Deuterium exchange | es |
dc.subject | Rhodium | es |
dc.subject | Silanes | es |
dc.subject | Deuterosilylation | es |
dc.subject | Catalysis | es |
dc.title | Large-scale preparation and labelling reactions of deuterated silanes | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/submittedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | CTQ2010‐17476 | es |
dc.relation.projectID | Consolider‐Ingenio 2010 CSD2007‐00006 | es |
dc.relation.projectID | FQM‐119 | es |
dc.relation.projectID | P09‐FQM‐4832 | es |
dc.relation.projectID | AP20080256 | es |
dc.relation.projectID | 22934 | es |
dc.relation.publisherversion | https://doi.org/10.1002/jlcr.1950 | es |
dc.identifier.doi | 10.1002/jlcr.1950 | es |
idus.format.extent | 25 | es |
dc.journaltitle | Journal of Labelled Compounds and Radiopharmaceuticals | es |
dc.publication.volumen | 55 | es |
dc.publication.initialPage | 29 | es |
dc.publication.endPage | 38 | es |