dc.creator | Mendoza, Irene | es |
dc.creator | Curado, Natalia | es |
dc.creator | Carrasco Delgado, Mario | es |
dc.creator | Álvarez González, Eleuterio | es |
dc.creator | Peloso, Riccardo | es |
dc.creator | Rodríguez, Amor | es |
dc.creator | Carmona Guzmán, Ernesto | es |
dc.date.accessioned | 2018-09-20T09:43:53Z | |
dc.date.available | 2018-09-20T09:43:53Z | |
dc.date.issued | 2015 | |
dc.identifier.citation | Mendoza, I., Curado, N., Carrasco Delgado, M., Álvarez González, E., Peloso, R., Rodríguez, A. y Carmona, E. (2015). Synthesis and structure of mixed carboxylate-aminopyridinate and -amidinate complexes of dimolybdenum and ditungsten. Inorganica Chimica Acta, 424, 120-128. | |
dc.identifier.issn | 0020-1693 | es |
dc.identifier.uri | https://hdl.handle.net/11441/78671 | |
dc.description.abstract | We describe in this paper the synthesis and structural characterization of dimolybdenum and ditungsten complexes with MM bonds derived from the metal–metal bonded tetracarboxylates [M2(O2CR)4] and incorporating one or two bulky aminopyridinate or amidinate ligands. The new compounds were isolated in good yields from reactions of the [Mo2(O2CR)4] (R = CF3, Me) and [W2(O2CCF3)4] metal precursors with the lithium salts of several aminopyridinate and amidinate ligands. They have formulations [M2()(O2CR)3] or [M2()2(O2CR)2] ( = bridging aminopyridinate or amidinate ligand) and were identified by microanalysis and common spectroscopic techniques. Nine of the newly reported complexes were additionally characterized by X-ray crystallography. | es |
dc.description.sponsorship | Ministerio de Ciencia e Innovación CTQ2010-15833, CTQ2011-23862-C02-01, Consolider-Ingenio 2010 CSD2007-0000 | es |
dc.description.sponsorship | Junta de Andalucía FQM-119, P09-FQM-5117 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Elsevier | es |
dc.relation.ispartof | Inorganica Chimica Acta, 424, 120-128. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Molybdenum | es |
dc.subject | Tungsten | es |
dc.subject | Carboxylate | es |
dc.subject | Aminopyridinate | es |
dc.subject | Amidinate | es |
dc.subject | Quadruple bond | es |
dc.title | Synthesis and structure of mixed carboxylate-aminopyridinate and -amidinate complexes of dimolybdenum and ditungsten | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/submittedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.relation.projectID | CTQ2010-15833 | es |
dc.relation.projectID | CTQ2011-23862-C02-01 | es |
dc.relation.projectID | Consolider-Ingenio 2010 CSD2007-0000 | es |
dc.relation.projectID | FQM-119 | es |
dc.relation.projectID | P09-FQM-5117 | es |
dc.relation.publisherversion | https://doi.org/10.1016/j.ica.2014.07.055 | es |
dc.identifier.doi | 10.1016/j.ica.2014.07.055 | es |
idus.format.extent | 19 | es |
dc.journaltitle | Inorganica Chimica Acta | es |
dc.publication.volumen | 424 | es |
dc.publication.initialPage | 120 | es |
dc.publication.endPage | 128 | es |