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Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition Metal Only Frustrated Lewis Pair

dc.creatorCampos, Jesúses
dc.date.accessioned2018-06-26T10:52:51Z
dc.date.available2018-06-26T10:52:51Z
dc.date.issued2017
dc.identifier.citationCampos, J. (2017). Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition Metal Only Frustrated Lewis Pair. Journal of the American Chemical Society, 139 (8), 2944-2947.
dc.identifier.issn0002-7863 (impreso)es
dc.identifier.issn1520-5126 (electrónico)es
dc.identifier.urihttps://hdl.handle.net/11441/76456
dc.description.abstractThe first example of a Frustrated Lewis Pair (FLP) solely constructed around transition metal centers is described in this work. We have focused on the established capacity of Au(I) and Pt(0) complexes to act as Lewis acidic and basic frag-ments, respectively, while employing sufficiently bulky PtBu3 and terphenyl phosphine ligands. This avoids formation of metallic Lewis adducts and confers the Au(I)/Pt(0) pair a remarkable capacity to activate dihydrogen and acetylene molecules in a fash-ion that closely resembles that of traditional main group FLP systems. As a consequence, unusual heterobimetallic Au(I)/Pt(II) complexes containing hydride (-H), acetylide (-C≡CH) and vinylene (-HC=CH-) bridges have been isolatedes
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherAmerican Chemical Societyes
dc.relation.ispartofJournal of the American Chemical Society, 139 (8), 2944-2947.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleDihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition Metal Only Frustrated Lewis Paires
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/submittedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Inorgánicaes
dc.relation.publisherversionhttp://dx.doi.org/10.1021/jacs.7b00491es
dc.identifier.doi10.1021/jacs.7b00491es
idus.format.extent5es
dc.journaltitleJournal of the American Chemical Societyes
dc.publication.volumen139es
dc.publication.issue8es
dc.publication.initialPage2944es
dc.publication.endPage2947es

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