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Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation

dc.creatorRíos Moreno, Pabloes
dc.creatorDíez, Josefinaes
dc.creatorLópez Serrano, Joaquínes
dc.creatorRodríguez, Amores
dc.creatorConejero, Salvadores
dc.date.accessioned2018-06-22T09:49:46Z
dc.date.available2018-06-22T09:49:46Z
dc.date.issued2016
dc.identifier.citationRíos, P., Díez, J., López Serrano, J., Rodríguez, A. y Conejero, S. (2016). Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation. Chemistry - A European Journal, 22, 16791-16795.
dc.identifier.issn0947-6539 (impreso)es
dc.identifier.issn1521-3765 (electrónico)es
dc.identifier.urihttps://hdl.handle.net/11441/76383
dc.description.abstractThe low-electron-count cationic platinum complex [Pt(ItBu’)(ItBu)][BAr], 1, interacts with primary and secondary silanes to form the corresponding σ-SiH complexes. According to DFT calculations, the most stable coordination mode is the uncommon η-SiH. The reaction of 1 with EtSiH leads to the X-ray structurally characterized 14-electron Pt species [Pt(SiEtH)(ItBu)][BAr], 2, which is stabilized by an agostic interaction. Complexes 1, 2, and the hydride [Pt(H)(ItBu)][BAr], 3, catalyze the hydrosilation of CO, leading to the exclusive formation of the corresponding silyl formates at room temperature.es
dc.description.sponsorshipMinisterio de Economía, Industria y Competitividad CTQ2013‐45011‐P and CTQ2014‐51912‐REDCes
dc.description.sponsorshipJunta de Andalucía FQM‐2126es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherJohn Wiley & Sonses
dc.relation.ispartofChemistry - A European Journal, 22, 16791-16795.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleCationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilationes
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/acceptedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Inorgánicaes
dc.relation.publisherversionhttps://doi.org/10.1002/chem.201603524es
dc.identifier.doi10.1002/chem.201603524es
idus.format.extent6es
dc.journaltitleChemistry - A European Journales
dc.publication.issue22es
dc.publication.initialPage16791es
dc.publication.endPage16795es
dc.contributor.funderMinisterio de Economia, Industria y Competitividad (MINECO). España
dc.contributor.funderJunta de Andalucía

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