| dc.creator | Ríos Moreno, Pablo | es |
| dc.creator | Díez, Josefina | es |
| dc.creator | López Serrano, Joaquín | es |
| dc.creator | Rodríguez, Amor | es |
| dc.creator | Conejero, Salvador | es |
| dc.date.accessioned | 2018-06-22T09:49:46Z | |
| dc.date.available | 2018-06-22T09:49:46Z | |
| dc.date.issued | 2016 | |
| dc.identifier.citation | Ríos, P., Díez, J., López Serrano, J., Rodríguez, A. y Conejero, S. (2016). Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation. Chemistry - A European Journal, 22, 16791-16795. | |
| dc.identifier.issn | 0947-6539 (impreso) | es |
| dc.identifier.issn | 1521-3765 (electrónico) | es |
| dc.identifier.uri | https://hdl.handle.net/11441/76383 | |
| dc.description.abstract | The low-electron-count cationic platinum complex [Pt(ItBu’)(ItBu)][BAr], 1, interacts with primary and secondary silanes to form the corresponding σ-SiH complexes. According to DFT calculations, the most stable coordination mode is the uncommon η-SiH. The reaction of 1 with EtSiH leads to the X-ray structurally characterized 14-electron Pt species [Pt(SiEtH)(ItBu)][BAr], 2, which is stabilized by an agostic interaction. Complexes 1, 2, and the hydride [Pt(H)(ItBu)][BAr], 3, catalyze the hydrosilation of CO, leading to the exclusive formation of the corresponding silyl formates at room temperature. | es |
| dc.description.sponsorship | Ministerio de Economía, Industria y Competitividad CTQ2013‐45011‐P and CTQ2014‐51912‐REDC | es |
| dc.description.sponsorship | Junta de Andalucía FQM‐2126 | es |
| dc.format | application/pdf | es |
| dc.language.iso | eng | es |
| dc.publisher | John Wiley & Sons | es |
| dc.relation.ispartof | Chemistry - A European Journal, 22, 16791-16795. | |
| dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
| dc.title | Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation | es |
| dc.type | info:eu-repo/semantics/article | es |
| dcterms.identifier | https://ror.org/03yxnpp24 | |
| dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
| dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
| dc.relation.publisherversion | https://doi.org/10.1002/chem.201603524 | es |
| dc.identifier.doi | 10.1002/chem.201603524 | es |
| idus.format.extent | 6 | es |
| dc.journaltitle | Chemistry - A European Journal | es |
| dc.publication.issue | 22 | es |
| dc.publication.initialPage | 16791 | es |
| dc.publication.endPage | 16795 | es |
| dc.contributor.funder | Ministerio de Economia, Industria y Competitividad (MINECO). España | |
| dc.contributor.funder | Junta de Andalucía | |
Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation
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