dc.creator | Melero Jiménez, Cristóbal | es |
dc.creator | Shishilov, Oleg N. | es |
dc.creator | Álvarez González, Eleuterio | es |
dc.creator | Palma Ramírez, María del Pilar | es |
dc.creator | Cámpora Pérez, Juan | es |
dc.date.accessioned | 2018-03-05T15:06:30Z | |
dc.date.available | 2018-03-05T15:06:30Z | |
dc.date.issued | 2012 | |
dc.identifier.citation | Melero Jiménez, C., Shishilov, O.N., Álvarez González, E., Palma Ramírez, M.d.P. y Cámpora Pérez, J. (2012). Well-defined alkylpalladium complexes with pyridine-carboxylate ligands as catalysts for the aerobic oxidation of alcohols. Dalton Transactions, 41 (46), 14087-14100. | |
dc.identifier.issn | 1477-9226 (impreso) | es |
dc.identifier.issn | 1477-9234 (electrónico) | es |
dc.identifier.uri | https://hdl.handle.net/11441/70784 | |
dc.description.abstract | Neophylpalladium complexes of the type [Pd(CH(2)CMe(2)Ph)(N-O)(L)], where N-O is picolinate or a related bidentate, monoanionic ligand (6-methylpyridine-2-carboxylate, quinoline-2-carboxylate, 2-pyridylacetate or pyridine-2-sulfonate) and L is pyridine or a pyridine derivative, efficiently catalyze the oxidation of a range of aliphatic, benzylic and allylic alcohols with oxygen, without requiring any additives. A versatile method is described which allows the synthesis of the above-mentioned complexes with a minimum synthetic effort from readily available materials. Comparison of the rates of oxidation of 1-phenylethanol with different catalysts reveals the influence of the structure of the bidentate N-O chelate and the monodentate ligand L on the catalytic performance of these complexes | es |
dc.description.sponsorship | Gobierno de España CTQ2009-11721 | es |
dc.description.sponsorship | Junta de Andalucía FQM6276 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry (Great Britain) | es |
dc.relation.ispartof | Dalton Transactions, 41 (46), 14087-14100. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Well-defined alkylpalladium complexes with pyridine-carboxylate ligands as catalysts for the aerobic oxidation of alcohols | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/submittedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.relation.projectID | CTQ2009-11721 | es |
dc.relation.projectID | FQM6276 | es |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c2dt31728a | es |
dc.identifier.doi | 10.1039/c2dt31728a | es |
idus.format.extent | 26 p. | es |
dc.journaltitle | Dalton Transactions | es |
dc.publication.volumen | 41 | es |
dc.publication.issue | 46 | es |
dc.publication.initialPage | 14087 | es |
dc.publication.endPage | 14100 | es |
dc.contributor.funder | Gobierno de España | |
dc.contributor.funder | Junta de Andalucía | |