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Artículo
Boryl-assisted hydrogenolysis of a nickel–methyl bond
| dc.creator | Curado Dianez, Natalia | es |
| dc.creator | Maya Díaz, Celia María | es |
| dc.creator | López Serrano, Joaquín | es |
| dc.creator | Rodríguez Iglesias, María Amor | es |
| dc.date.accessioned | 2018-02-07T15:24:07Z | |
| dc.date.available | 2018-02-07T15:24:07Z | |
| dc.date.issued | 2014 | |
| dc.identifier.citation | Curado Dianez, N., Maya Díaz, C.M., López Serrano, J. y Rodríguez Iglesias, M.A. (2014). Boryl-assisted hydrogenolysis of a nickel–methyl bond. Chemical Communications, 50, 15718-15721. | |
| dc.identifier.issn | 1359-7345 (impreso) | es |
| dc.identifier.issn | 1364-548X (electrónico) | es |
| dc.identifier.uri | https://hdl.handle.net/11441/70093 | |
| dc.description.abstract | A stable Nickel(II) methyl complex containing a diphosphinoboryl (PBP) pincer ligand is described. Mechanistic studies on the hydrogenolysis of the Ni-Me bond suggest a metal ligand cooperation mechanism that involves the intermediacy of a - B‒H Ni(0) species that further undergoes B‒H oxidative addition to form a Ni(II) hydride complex. | es |
| dc.format | application/pdf | es |
| dc.language.iso | eng | es |
| dc.publisher | Royal Society of Chemistry (Great Britain) | es |
| dc.relation.ispartof | Chemical Communications, 50, 15718-15721. | |
| dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
| dc.title | Boryl-assisted hydrogenolysis of a nickel–methyl bond | es |
| dc.type | info:eu-repo/semantics/article | es |
| dcterms.identifier | https://ror.org/03yxnpp24 | |
| dc.type.version | info:eu-repo/semantics/submittedVersion | es |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
| dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
| dc.relation.publisherversion | http://dx.doi.org/ 10.1039/C4CC07616H | es |
| dc.identifier.doi | 10.1039/C4CC07616H | es |
| idus.format.extent | 4 p. | es |
| dc.journaltitle | Chemical Communications | es |
| dc.publication.volumen | 50 | es |
| dc.publication.initialPage | 15718 | es |
| dc.publication.endPage | 15721 | es |
| Ficheros | Tamaño | Formato | Ver | Descripción |
|---|---|---|---|---|
| Boryl-Assisted Hydrogenolysis.pdf | 1.437Mb | 
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