dc.creator | Scheuermann, Margaret L. | es |
dc.creator | Grice, Kyle A. | es |
dc.creator | Ruppel, Matthew J. | es |
dc.creator | Roselló Merino, Marta | es |
dc.creator | Kaminsky, Werner | es |
dc.creator | Goldberg, Karen I. | es |
dc.date.accessioned | 2018-01-09T17:31:09Z | |
dc.date.available | 2018-01-09T17:31:09Z | |
dc.date.issued | 2014 | |
dc.identifier.citation | Scheuermann, M.L., Grice, K.A., Ruppel, M.J., Roselló Merino, M., Kaminsky, W. y Goldberg, K.I. (2014). Hemilability of P(X)N-type ligands (X = O, N–H): rollover cyclometalation and benzene C–H activation from (P(X)N)PtMe2 complexes. Dalton Transactions, 43, 12018-. | |
dc.identifier.issn | 1477-9226 (impreso) | es |
dc.identifier.issn | 1477-9234 (electrónico) | es |
dc.identifier.uri | http://hdl.handle.net/11441/68544 | |
dc.description.abstract | The thermolyses of (tBuP(O)N)PtMe2 (1, tBuP(O)N = (di-tert-butylphosphinito)pyridine) and (tBuP(N–H)N)PtMe2 (3, tBuP(N–H)N = (di-tert-butylphosphino)-2-aminopyridine) in benzene-d6 were investigated. With (tBuP(O) N)PtMe2, the product of a rollover cyclometalation of the pyridyl ring was observed in 80% yield along with formation of CH4. In contrast, thermolysis of (tBuP(N–H)N)PtMe2 resulted in competing rollover cyclometalation and intermolecular benzene C–H activation with production of a mixture of CH4 and CH3D | es |
dc.description.sponsorship | National Science Foundation CHE-1012045, DGE-0718124 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry (Great Britain) | es |
dc.relation.ispartof | Dalton Transactions, 43, 12018-. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Hemilability of P(X)N-type ligands (X = O, N–H): rollover cyclometalation and benzene C–H activation from (P(X)N)PtMe2 complexes | es |
dc.type | info:eu-repo/semantics/article | es |
dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.relation.projectID | CHE-1012045 | es |
dc.relation.projectID | DGE-0718124 | es |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c4dt01143k | es |
dc.identifier.doi | 10.1039/c4dt01143k | es |
idus.format.extent | 8 p. | es |
dc.journaltitle | Dalton Transactions | es |
dc.publication.volumen | 43 | es |
dc.publication.initialPage | 12018 | es |
dc.contributor.funder | National Science Foundation (NSF). United States | |