dc.creator | Vivancos Ureña, Ángela | es |
dc.creator | Vattier Lagarrigue, María Florencia | es |
dc.creator | López Serrano, Joaquín | es |
dc.creator | Paneque Sosa, Margarita | es |
dc.creator | López Poveda, Manuel | es |
dc.creator | Álvarez González, Eleuterio | es |
dc.date.accessioned | 2017-11-20T18:10:24Z | |
dc.date.available | 2017-11-20T18:10:24Z | |
dc.date.issued | 2015 | |
dc.identifier.citation | Vivancos Ureña, Á., Vattier Lagarrigue, M.F., López Serrano, J., Paneque Sosa, M., López Poveda, M. y Álvarez González, E. (2015). A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition. Journal of the American Chemical Society, 137 (12), 4074-4077. https://doi.org/10.1021/jacs.5b01532. | |
dc.identifier.issn | 0002-7863 (impreso) | es |
dc.identifier.issn | 1520-5126 (electrónico) | es |
dc.identifier.uri | http://hdl.handle.net/11441/66280 | |
dc.description.abstract | The TpMe2Ir(III) complex 1-OH2 (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water and an iridium-bonded alkenyl moiety (−C(R)═C(R)–(R=CO2Me)) as part of a benzo-annulated five-membered iridacycle, reacts readily with the conjugated dienes butadiene and 2,3-dimethylbutadiene to afford the corresponding Diels–Alder products. Experimental and DFT studies are in accordance with an initial [4 + 3] cyclometalation reaction between the diene and the five-coordinated 16-electron organometallic fragment 1 (generated from 1-OH2 by facile water dissociation). The reaction can be extended to a related TpIr(III) complex (Tp = hydrotris(pyrazolyl)borate) that also features a labile ligand (i.e., 2-THF). | es |
dc.description.sponsorship | Ministerio de Economía y Competitividad CTQ2014- 51912-REDC | es |
dc.description.sponsorship | Junta de Andalucía FQM-119, P09-FQM-4832 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | American Chemical Society | es |
dc.relation.ispartof | Journal of the American Chemical Society, 137 (12), 4074-4077. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.contributor.affiliation | Instituto de Investigaciones Químicas (IIQ) – CIC Cartuja | es |
dc.relation.projectID | CTQ2014- 51912-REDC | es |
dc.relation.projectID | FQM-119 | es |
dc.relation.projectID | P09-FQM-4832 | es |
dc.relation.publisherversion | http://dx.doi.org/10.1021/jacs.5b01532 | es |
dc.identifier.doi | 10.1021/jacs.5b01532 | es |
idus.format.extent | 5 p. | es |
dc.journaltitle | Journal of the American Chemical Society | es |
dc.publication.volumen | 137 | es |
dc.publication.issue | 12 | es |
dc.publication.initialPage | 4074 | es |
dc.publication.endPage | 4077 | es |
dc.contributor.funder | Ministerio de Economía y Competitividad (MINECO). España | |
dc.contributor.funder | Junta de Andalucía | |