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dc.creatorLópez Santos, Lauraes
dc.creatorPaneque Sosa, Margaritaes
dc.creatorMereiter, Kurtes
dc.date.accessioned2017-04-11T12:05:17Z
dc.date.available2017-04-11T12:05:17Z
dc.date.issued2013
dc.identifier.citationLópez Santos, L., Paneque Sosa, M. y Mereiter, K. (2013). Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl) hydroborato]iridium(III) chloroform monosolvate. Acta Crystallographica Section E: Structure Reports Online, 69 (4), 224-225.
dc.identifier.issn1600-5368es
dc.identifier.urihttp://hdl.handle.net/11441/57482
dc.description.abstractIn the title compound, [Ir(C15H22BN6)(C8H7O)Cl]·CHCl3, the Ir atom is formally trivalent and is coordinated in a slightly distorted octahedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir Ccarbene bond is strong and short and exerts a notable effect on the trans-Ir—N bond, which is about 0.10 A˚ longer than the two other Ir—N bonds. The chloroform solvent molecule is anchored via a weak C—H·· ·Cl hydrogen bond to the Cl atom of the Ir complex molecule. In the crystal, the constituents adopt a layer-like arrangement parallel to (010) and are held together by weak intermolecular C—H·· ·Cl hydrogen bonds, as well as weak Cl·· ·Cl [3.498 (2) A˚ ] and Cl·· ·JT [3.360 (4) A˚ ] inter- actions. A weak intramolecular C—H·· ·O hydrogen bond is also observedes
dc.description.sponsorshipFEDER CTQ2010–17476es
dc.description.sponsorshipConsolider-Ingenio 2010 CSD2007–00006es
dc.description.sponsorshipJunta de Andalucía FQM-119 P09-FQM-4832es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherInternational Union of Crystallographyes
dc.relation.ispartofActa Crystallographica Section E: Structure Reports Online, 69 (4), 224-225.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleChlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl) hydroborato]iridium(III) chloroform monosolvatees
dc.typeinfo:eu-repo/semantics/articlees
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessrightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Inorgánicaes
dc.relation.projectIDCTQ2010–17476es
dc.relation.projectIDCSD2007–00006es
dc.relation.projectIDFQM-119es
dc.relation.projectIDP09-FQM-4832es
dc.relation.publisherversion10.1107/S1600536813007344es
idus.format.extent14 p.es
dc.journaltitleActa Crystallographica Section E: Structure Reports Onlinees
dc.publication.volumen69es
dc.publication.issue4es
dc.publication.initialPage224es
dc.publication.endPage225es

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