dc.creator | Ye, Runping | es |
dc.creator | Ma, Lixuan | es |
dc.creator | Hong, Xiaoling | es |
dc.creator | Ramírez Reina, Tomás | es |
dc.creator | Luo, Wenhao | es |
dc.creator | Kang, Liqun | es |
dc.creator | Liu, Jian | es |
dc.date.accessioned | 2024-05-28T10:28:12Z | |
dc.date.available | 2024-05-28T10:28:12Z | |
dc.date.issued | 2023-11-30 | |
dc.identifier.citation | Ye, R., Ma, L., Hong, X., Ramírez Reina, T., Luo, W., Kang, L. y Liu, J. (2023). Boosting Low-Temperature CO2 Hydrogenation over Ni-based Catalysts by Tuning Strong Metal-Support Interactions.. Angewandte Chemie - International Edition, 63 (3), e202317669. https://doi.org/10.1002/anie.202317669. | |
dc.identifier.issn | 1521-3773 | es |
dc.identifier.issn | 1433-7851 | es |
dc.identifier.uri | https://hdl.handle.net/11441/159125 | |
dc.description.abstract | Rational design of low-cost and efficient transition-metal catalysts for low-temperature CO2 activation is significant and poses great challenges. Herein, a strategy via regulating the local electron density of active sites is developed to boost CO2 methanation that normally requires >350 °C for commercial Ni catalysts. An optimal Ni/ZrO2 catalyst affords an excellent low-temperature performance hitherto, with a CO2 conversion of 84.0 %, CH4 selectivity of 98.6 % even at 230 °C and GHSV of 12,000 mL g−1 h−1 for 106 h, reflecting one of the best CO2 methanation performance to date on Ni-based catalysts. Combined a series of in situ spectroscopic characterization studies reveal that re-constructing monoclinic-ZrO2 supported Ni species with abundant oxygen vacancies can facilitate CO2 activation, owing to the enhanced local electron density of Ni induced by the strong metal-support interactions. These findings might be of great aid for construction of robust catalysts with an enhanced performance for CO2 emission abatement and beyond. | es |
dc.description.sponsorship | National Natural Science Foundation of China (NSFC) 22005296 21868016 | es |
dc.description.sponsorship | Natural Science Foundation of Liaoning Province 2020-YQ-01 | es |
dc.description.sponsorship | Natural Science Foundation of Shanxi Province for Distinguished Young Scholar 20210302121005 | es |
dc.description.sponsorship | Natural Science Foundation of Jiangxi Province for Distinguished Young Scholars 20232ACB213001 | es |
dc.description.sponsorship | Thousand Talents Plan of Jiangxi Province jxsq2023101072 | es |
dc.description.sponsorship | Natural Science Foundation of Chongqing CSTB2022NSCQ-MSX0231 | es |
dc.description.sponsorship | European Commission through the BIOALL project 101008058, 2022YFA1504500, 2021YFA1502804 | es |
dc.format | application/pdf | es |
dc.format.extent | 11 | es |
dc.language.iso | eng | es |
dc.publisher | Wiley-V C H Verlag GMBH | es |
dc.relation.ispartof | Angewandte Chemie - International Edition, 63 (3), e202317669. | |
dc.rights | Atribución 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | * |
dc.title | Boosting Low-Temperature CO2 Hydrogenation over Ni-based Catalysts by Tuning Strong Metal-Support Interactions. | es |
dc.type | info:eu-repo/semantics/article | es |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | 22005296 | es |
dc.relation.projectID | 21868016 | es |
dc.relation.projectID | 2020-YQ-01 | es |
dc.relation.projectID | 20210302121005 | es |
dc.relation.projectID | 20232ACB213001 | es |
dc.relation.projectID | jxsq2023101072 | es |
dc.relation.projectID | CSTB2022NSCQ-MSX0231 | es |
dc.relation.projectID | 101008058 | es |
dc.relation.projectID | 2022YFA1504500 | es |
dc.relation.projectID | 2021YFA1502804 | es |
dc.relation.publisherversion | https://doi.org/10.1002/anie.202317669 | es |
dc.identifier.doi | 10.1002/anie.202317669 | es |
dc.journaltitle | Angewandte Chemie - International Edition | es |
dc.publication.volumen | 63 | es |
dc.publication.issue | 3 | es |
dc.publication.initialPage | e202317669 | es |
dc.contributor.funder | National Natural Science Foundation of China (NSFC) | es |
dc.contributor.funder | Natural Science Foundation of Liaoning Province | es |
dc.contributor.funder | Natural Science Foundation of Shanxi Province for Distinguished Young Scholar | es |
dc.contributor.funder | Natural Science Foundation of Jiangxi Province for Distinguished Young Scholars | es |
dc.contributor.funder | Thousand Talents Plan of Jiangxi Province | es |
dc.contributor.funder | Natural Science Foundation of Chongqing | es |
dc.contributor.funder | European Commission through the BIOALL project | es |
dc.contributor.funder | National Key R&D Program of China | es |