dc.creator | Gandara Loe, Jesús | es |
dc.creator | Pinzón Peña, Alejandro | es |
dc.creator | Martín Espejo, Juan Luis | es |
dc.creator | Bobadilla Baladrón, Luis Francisco | es |
dc.creator | Ramírez Reina, Tomás | es |
dc.creator | Pastor Pérez, Laura | es |
dc.date.accessioned | 2024-05-09T14:29:37Z | |
dc.date.available | 2024-05-09T14:29:37Z | |
dc.date.issued | 2023 | |
dc.identifier.citation | Gandara Loe, J., Pinzón Peña, A., Martín Espejo, J.L., Bobadilla Baladrón, L.F., Ramírez Reina, T. y Pastor Pérez, L. (2023). MIL-100(Fe)-Derived Catalysts for CO2 Conversion Via Low- and High-Temperature Reverse Water-gas Shift Reaction. Heliyon, 9 (5), e16070. https://doi.org/10.1016/j.heliyon.2023.e16070. | |
dc.identifier.issn | 2405-8440 | es |
dc.identifier.issn | 2405-8440 | es |
dc.identifier.uri | https://hdl.handle.net/11441/158014 | |
dc.description.abstract | Fe-derived catalysts were synthesized by the pyrolysis of MIL-100 (Fe) metal-organic framework (MOF) and evaluated in the reverse water-gas shift (RWGS) reaction. The addition of Rh as a dopant by in-situ incorporation during the synthesis and wet impregnation was also considered. Our characterization data showed that the main active phase was a mixture of α-Fe, Fe3C, and Fe3O4 in all the catalysts evaluated. Additionally, small Rh loading leads to a decrease in the particle size in the active phase. Despite all three catalysts showing commendable CO selectivity levels, the C@Fe* catalyst showed the most promising performance at a temperature below 500 °C, attributed to the in-situ incorporation of Rh during the synthesis. Overall, this work showcases a strategy for designing novel Fe MOF-derived catalysts for RWGS reaction, opening new research opportunities for CO2 utilization schemes. | es |
dc.description.sponsorship | Ministerio de Ciencia e Innovación PID2019-108502 R J-I00, IJC2019-040560-I | es |
dc.description.sponsorship | Junta de Andalucía P20_00667 | es |
dc.format | application/pdf | es |
dc.format.extent | 10 p. | es |
dc.language.iso | eng | es |
dc.publisher | Elsevier | es |
dc.relation.ispartof | Heliyon, 9 (5), e16070. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | CO2 conversion | es |
dc.subject | Fe-based catalysts | es |
dc.subject | MOF-derived catalysts | es |
dc.subject | RWGS reaction | es |
dc.title | MIL-100(Fe)-Derived Catalysts for CO2 Conversion Via Low- and High-Temperature Reverse Water-gas Shift Reaction | es |
dc.type | info:eu-repo/semantics/article | es |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | PID2019-108502 R J-I00 | es |
dc.relation.projectID | IJC2019-040560-I | es |
dc.relation.projectID | P20_00667 | es |
dc.relation.publisherversion | https://dx.doi.org/10.1016/j.heliyon.2023.e16070 | es |
dc.identifier.doi | 10.1016/j.heliyon.2023.e16070 | es |
dc.journaltitle | Heliyon | es |
dc.publication.volumen | 9 | es |
dc.publication.issue | 5 | es |
dc.publication.initialPage | e16070 | es |
dc.contributor.funder | Ministerio de Ciencia e Innovación (MICIN). España | es |
dc.contributor.funder | Junta de Andalucía | es |