Artículo
Influence of the ionic liquid presence on the selective oxidation of glucose over molybdenum based catalysts
Autor/es | Megías Sayago, Cristina
Carrasco Carrasco, Carlos Jesús Ivanova, Svetlana Montilla Ramos, Francisco Javier Galindo del Pozo, Agustín Odriozola Gordón, José Antonio |
Departamento | Universidad de Sevilla. Departamento de Química Inorgánica |
Fecha de publicación | 2016-12-01 |
Fecha de depósito | 2024-01-12 |
Publicado en |
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Resumen | Two different approaches are proposed in this work in order to study the influence of the ionic liquid presence in the reaction of glucose oxidation by H2O2 in mild conditions. The ionic liquids are applied either as a ... Two different approaches are proposed in this work in order to study the influence of the ionic liquid presence in the reaction of glucose oxidation by H2O2 in mild conditions. The ionic liquids are applied either as a solvent by using homogeneous Mo based catalyst, [Mo(O)(O2)2(H2O)n] complex, or by using it as an integral part of a heterogeneous catalyst, organic inorganic hybrids based on Mo Keggin structure. Both catalytic strategies resulted in acceptable glucose transformation degrees but lead to different oxidation products depending on the role of the ionic liquid. The hybrid approach restrains the number of the received products being the most selective one. A detailed study of the effect of the hybrid nature and reaction conditions is proposed in the second part of this study. |
Agencias financiadoras | Junta de Andalucía Ministerio de Economía y Competitividad (MINECO). España |
Identificador del proyecto | FQM-7079
ENE201347880-C3-2-R |
Cita | Megías Sayago, C., Carrasco Carrasco, C.J., Ivanova, S., Montilla Ramos, F.J., Galindo del Pozo, A. y Odriozola Gordón, J.A. (2016). Influence of the ionic liquid presence on the selective oxidation of glucose over molybdenum based catalysts. Catalysis Today, 278, 82-90. https://doi.org/10.1016/j.cattod.2016.06.040. |
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