Artículo
Enhancement of the Magnetic Refrigerant Capacity in Partially Amorphous Fe 70Zr 30 Powders Obtained by Mechanical Alloying
Autor/es | Blázquez Gámez, Javier Sebastián
Franco García, Victorino Conde Amiano, Alejandro |
Departamento | Universidad de Sevilla. Departamento de Física de la Materia Condensada |
Fecha de publicación | 2012 |
Fecha de depósito | 2023-06-13 |
Publicado en |
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Resumen | After mechanical alloying Fe 70Zr 30 composition from pure starting powders, an amorphous phase with Curie temperature T C = 244 K and an intermetallic compound (that should be non-stoichiometric Zr-rich fcc Fe 2Zr phase) ... After mechanical alloying Fe 70Zr 30 composition from pure starting powders, an amorphous phase with Curie temperature T C = 244 K and an intermetallic compound (that should be non-stoichiometric Zr-rich fcc Fe 2Zr phase) with T C = 355 K are formed. Residual α-Fe crystallites are also found. The multiphase character of this system yields a non-monotonic dependence of the magnetocaloric effect (characterized by the refrigerant capacity, RC) on the fraction of phases. Among the samples studied in this work, RC is enhanced for samples with the highest fraction of intermetallic compound, although the maximum magnetic entropy change monotonically decreases with the increase of the fraction of this phase. This behaviour agrees with the predicted one for biphasic systems. |
Agencias financiadoras | Ministerio de Ciencia e Innovación (MICIN). España European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER) Junta de Andalucía Office of Naval Research (ONR). United States |
Identificador del proyecto | MAT 2010-20537
P10-FQM-6462 N00014-11-1-0311 |
Cita | Blázquez Gámez, J.S., Franco García, V. y Conde Amiano, A. (2012). Enhancement of the Magnetic Refrigerant Capacity in Partially Amorphous Fe 70Zr 30 Powders Obtained by Mechanical Alloying. Intermetallics, 26, 52-56. https://doi.org/10.1016/j.intermet.2012.03.011. |
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