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A dicoordinate gold(i)–ethylene complex

dc.creatorNavarro, Miqueles
dc.creatorMiranda Pizarro, Juanes
dc.creatorMoreno Díaz, Juan Josées
dc.creatorNavarro Gilabert, Carloses
dc.creatorFernández, Israeles
dc.creatorCampos, Jesúses
dc.date.accessioned2023-06-09T11:46:37Z
dc.date.available2023-06-09T11:46:37Z
dc.date.issued2021
dc.identifier.citationNavarro, M., Miranda Pizarro, J., Moreno Díaz, J.J., Navarro Gilabert, C., Fernández, I. y Campos, J. (2021). A dicoordinate gold(i)–ethylene complex. Chemical Communications, 57, 9280-9283. https://doi.org/10.1039/D1CC02769G.
dc.identifier.issn1364-548X impresoes
dc.identifier.issn1359-7345 electrónicoes
dc.identifier.urihttps://hdl.handle.net/11441/147040
dc.description.abstractThe use of the exceptionally bulky tris-2-(4,40 -di-tert-butylbiphenylyl) phosphine ligand allows the isolation and complete characterization of the first dicoordinate gold(I)–ethylene adduct, filling a missing fundamental piece on the organometallic chemistry of gold. Besides, the bonding situation of this species has been investigated by means of state-of-the-art Density Functional Theory (DFT) calculations indicating that p-backdonation plays a minor role compared with tricoordinate analogueses
dc.description.sponsorshipEuropean Research Council (ERC Starting Grant, CoopCat, Project 756575)es
dc.description.sponsorshipe Spanish Ministry of Science and Innovation (Projects PID2019- 110856GA-I00, PID2019-106184GB-I00, RED2018-102387-T and FJC2018-035514-I )es
dc.formatapplication/pdfes
dc.format.extent4 p.es
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.relation.ispartofChemical Communications, 57, 9280-9283.
dc.rightsAtribución 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.titleA dicoordinate gold(i)–ethylene complexes
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Inorgánicaes
dc.relation.projectID756575es
dc.relation.projectIDPID2019-110856GA-I00es
dc.relation.projectIDPID2019-106184GB-I00es
dc.relation.projectIDRED2018-102387-Tes
dc.relation.projectIDFJC2018-035514-Ies
dc.relation.publisherversionhttps://doi.org/10.1039/D1CC02769Ges
dc.identifier.doi10.1039/D1CC02769Ges
dc.journaltitleChemical Communicationses
dc.publication.volumen57es
dc.publication.initialPage9280es
dc.publication.endPage9283es
dc.contributor.funderEuropean Research Council (ERC)es
dc.contributor.funderMinisterio de Ciencia e Innovación (MICIN). Españaes

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