Article
Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes
Author/s | Fernández Cestau, Julio
Rocchigiani, Luca Pintus, Anna Jiménez Rama, Raquel Budzelaar, Peter H. M. Bochmann, Manfred |
Department | Universidad de Sevilla. Departamento de Química Inorgánica |
Publication Date | 2018 |
Deposit Date | 2023-04-04 |
Published in |
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Abstract | Isocyanides insert into gold(III)–hydrogen bonds to give the first
examples of gold iminoformyl complexes. The reaction is initiated
by catalytic amounts of radicals; DFT calculations indicate that this
is an equilibrium ... Isocyanides insert into gold(III)–hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(II) intermediate |
Citation | Fernández Cestau, J., Rocchigiani, L., Pintus, A., Jiménez Rama, R., Budzelaar, P.H.M. y Bochmann, M. (2018). Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes. Chemical Communications, 54 (81), 11447-11450. https://doi.org/10.1039/c8cc06409a. |
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