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dc.creatorMonti, Andreaes
dc.creatorJiménez Rama, Raqueles
dc.creatorGómez, Beatrizes
dc.creatorMaya Díaz, Celia Maríaes
dc.creatorÁlvarez González, Eleuterioes
dc.creatorCarmona Guzmán, Ernestoes
dc.creatorNicasio Jaramillo, María del Carmenes
dc.date.accessioned2023-03-06T16:07:53Z
dc.date.available2023-03-06T16:07:53Z
dc.date.issued2021
dc.identifier.citationMonti, A., Jiménez Rama, R., Gómez, B., Maya Díaz, C.M., Álvarez González, E., Carmona Guzmán, E. y Nicasio Jaramillo, M.d.C. (2021). N-substituted Aminobiphenyl Palladacycles Stabilized by Dialkylterphenyl Phosphanes: Preparation and Applications in C[sbnd]N Cross-coupling Reactions. Inorganica Chimica Acta, 518, 120214. https://doi.org/10.1016/j.ica.2020.120214.
dc.identifier.issn0020-1693es
dc.identifier.issn1873-3255es
dc.identifier.urihttps://hdl.handle.net/11441/143187
dc.description.abstractNeutral and cationic N-methyl- and N-phenyl-2-aminobiphenyl methanesulfonate palladacycles stabilized with dialkylterphenyl phosphanes have been prepared and characterized. Neutral structures are favored with the less bulky phosphane PMe2ArXyl2, L1, while more sterically demanding ligands PiPr2ArXyl2, L3, and PCyp2ArXyl2 (Cyp = cyclopentyl), L4, lead to cationic complexes in which the phosphane exhibits a bidentate κ1-P, η1-Carene coordination mode involving one of the ipso carbon atoms of a flanking terphenyl aryl ring. The complexes were evaluated for activity in C[sbnd]N cross-coupling reactions and [Pd(N-methyl-2-aminobiphenyl)L4](OMs) (OMs = mesylate) was identified as the most efficient precatalyst, facilitating the coupling of aryl chlorides with secondary and primary amines and indoles.es
dc.description.sponsorshipMinisterio de Economía y Competitividad CTQ2017-82893-C2-2-Res
dc.description.sponsorshipJunta de Andalucía US-1262266es
dc.formatapplication/pdfes
dc.format.extent16 p.es
dc.language.isoenges
dc.publisherElsevieres
dc.relation.ispartofInorganica Chimica Acta, 518, 120214.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectAryl aminationes
dc.subjectCross-couplinges
dc.subjectPalladacycleses
dc.subjectPalladium catalysises
dc.subjectPhosphane ligandses
dc.titleN-substituted Aminobiphenyl Palladacycles Stabilized by Dialkylterphenyl Phosphanes: Preparation and Applications in C[sbnd]N Cross-coupling Reactionses
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/acceptedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Inorgánicaes
dc.relation.projectIDCTQ2017-82893-C2-2-Res
dc.relation.projectIDUS-1262266es
dc.relation.publisherversionhttps://dx.doi.org/10.1016/j.ica.2020.120214es
dc.identifier.doi10.1016/j.ica.2020.120214es
dc.journaltitleInorganica Chimica Actaes
dc.publication.volumen518es
dc.publication.initialPage120214es
dc.contributor.funderMinisterio de Economía y Competitividad (MINECO). Españaes
dc.contributor.funderJunta de Andalucíaes

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