LPdCl2(amine) Complexes Supported by Terphenyl Phosphanes: Applications in Aryl Amination Reactions

Santamaría Gallardo, Nazaret; Velasco, C.; Marín Gómez,  Mario; Maya Díaz, Celia María; Nicasio Jaramillo, María del Carmen

doi:10.1039/d2dt01354a

Artículo

dc.creator	Santamaría Gallardo, Nazaret	es
dc.creator	Velasco, C.	es
dc.creator	Marín Gómez, Mario	es
dc.creator	Maya Díaz, Celia María	es
dc.creator	Nicasio Jaramillo, María del Carmen	es
dc.date.accessioned	2023-03-06T15:18:18Z
dc.date.available	2023-03-06T15:18:18Z
dc.date.issued	2022
dc.identifier.citation	Santamaría Gallardo, N., Velasco, C., Marín Gómez, ., Maya Díaz, C.M. y Nicasio Jaramillo, M.d.C. (2022). LPdCl2(amine) Complexes Supported by Terphenyl Phosphanes: Applications in Aryl Amination Reactions. Dalton Transactions, 51 (41), 15734-15740. https://doi.org/10.1039/d2dt01354a.
dc.identifier.issn	1477-9226	es
dc.identifier.issn	1477-9234	es
dc.identifier.uri	https://hdl.handle.net/11441/143183
dc.description.abstract	Despite the excellent catalytic properties display by NHC-Pd-PEPPSI complexes in cross-coupling, phosphane analogs have been barely screened. In this work, we report the synthesis and characterization of a series of LPdCl2(amine) complexes bearing dialkylterphenyl phosphanes (PR2Ar′) and pyridine or morpholine ligands. The novel compounds have been tested as precatalysts in aryl amination reactions. The complex [(PCyp2ArXyl2)PdCl2(morpholine)] shows the best catalytic activity allowing the room-temperature coupling of aryl bromides and chlorides with aniline.	es
dc.description.sponsorship	Ministerio de Ciencia e Innovación PID2020-113797R	es
dc.description.sponsorship	Junta de Andalucía P20_00624	es
dc.description.sponsorship	European Commission (EC). Fondo Europeo de Desarrollo Regional US-1262266	es
dc.format	application/pdf	es
dc.format.extent	7 p.	es
dc.language.iso	eng	es
dc.publisher	Royal Society of Chemistry	es
dc.relation.ispartof	Dalton Transactions, 51 (41), 15734-15740.
dc.rights	Attribution-NonCommercial-NoDerivatives 4.0 Internacional	*
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/	*
dc.title	LPdCl2(amine) Complexes Supported by Terphenyl Phosphanes: Applications in Aryl Amination Reactions	es
dc.type	info:eu-repo/semantics/article	es
dcterms.identifier	https://ror.org/03yxnpp24
dc.type.version	info:eu-repo/semantics/acceptedVersion	es
dc.rights.accessRights	info:eu-repo/semantics/openAccess	es
dc.contributor.affiliation	Universidad de Sevilla. Departamento de Química Inorgánica	es
dc.relation.projectID	PID2020-113797R	es
dc.relation.projectID	P20_00624	es
dc.relation.projectID	US-1262266	es
dc.date.embargoEndDate	2023-09-26
dc.relation.publisherversion	https://dx.doi.org/10.1039/d2dt01354a	es
dc.identifier.doi	10.1039/d2dt01354a	es
dc.journaltitle	Dalton Transactions	es
dc.publication.volumen	51	es
dc.publication.issue	41	es
dc.publication.initialPage	15734	es
dc.publication.endPage	15740	es
dc.contributor.funder	Ministerio de Ciencia e Innovación (MICIN). España	es
dc.contributor.funder	Junta de Andalucía	es
dc.contributor.funder	European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER)	es

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