Artículo
A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
Autor/es | Hidalgo, Nereida
De la Cruz Martínez, Felipe Martín García, María Trinidad Nicasio Jaramillo, María del Carmen Campos Manzano, Jesús |
Departamento | Universidad de Sevilla. Departamento de Química Inorgánica |
Fecha de publicación | 2022 |
Fecha de depósito | 2023-03-06 |
Publicado en |
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Resumen | A series of Au(I)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the ... A series of Au(I)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative manner. The steric bulk of the terphenyl phosphines that stabilize both fragments allows for the isolation of a rather unique and highly distorted cis-type dihydride platinum(II) structure. |
Agencias financiadoras | Ministerio de Ciencia, Innovación y Universidades (MICINN). España European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER) |
Identificador del proyecto | CTQ2014-52769-C3-3-R
CTQ2017-82893-C2-2-R |
Cita | Hidalgo, N., De la Cruz Martínez, F., Martín García, M.T., Nicasio Jaramillo, M.d.C. y Campos Manzano, J. (2022). A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation. Chemical Communications, 58 (65), 9144-9147. https://doi.org/10.1039/d2cc03089f. |
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