dc.creator | Martínez Prieto, Luis Miguel | es |
dc.creator | Cámpora, Juan | es |
dc.date.accessioned | 2023-01-27T17:35:08Z | |
dc.date.available | 2023-01-27T17:35:08Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Martínez Prieto, L.M. y Cámpora, J. (2020). Nickel and Palladium Complexes with Reactive σ-Metal-Oxygen Covalent Bonds. Israel Journal of Chemistry, 60 (3-4), 373-393. https://doi.org/10.1002/ijch.202000001. | |
dc.identifier.issn | 0021-2148 | es |
dc.identifier.issn | 1869-5868 | es |
dc.identifier.uri | https://hdl.handle.net/11441/142068 | |
dc.description.abstract | This article reviews the chemistry of nickel and palladium complexes with terminally bound hydroxide and alkoxide ligands. The research carried out in our group is discussed in the context of the general literature. It is shown that suitable methods of synthesis, combined with the choice of adequate ligands allow the isolation of a range of stable complexes. This has enabled a detailed investigation of the chemical reactivity of the M−O bonds, once believed to be intrinsically weak. The elucidation of trends in thermodynamic stability and kinetic lability is the key for a better understanding of the reactivity of this class of compounds, that combines basic and nucleophilic properties with typical organometallic patterns, like β-hydrogen elimination. Based on reversible acid-base exchange and CO2 insertion reactions, we discuss how the polarity of the M-OR bonds influence their relative stability, their hydrolytic sensitivity and their tendency to react with electrophiles. | es |
dc.description.sponsorship | Ministerio de Ciencia, Innovación y Universidades PGC2018-095768-B-100 | es |
dc.description.sponsorship | Universidad Politécnica de Valencia PAID-06-18 | es |
dc.format | application/pdf | es |
dc.format.extent | 35 p. | es |
dc.language.iso | eng | es |
dc.publisher | Wiley-Blackwell | es |
dc.relation.ispartof | Israel Journal of Chemistry, 60 (3-4), 373-393. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | CO2 fixation | es |
dc.subject | Nickel | es |
dc.subject | O-Ligands | es |
dc.subject | Palladium | es |
dc.subject | β-Hydrogen Elimination | es |
dc.title | Nickel and Palladium Complexes with Reactive σ-Metal-Oxygen Covalent Bonds | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | PGC2018-095768-B-100 | es |
dc.relation.projectID | PAID-06-18 | es |
dc.relation.publisherversion | https://doi.org/10.1002/ijch.202000001 | es |
dc.identifier.doi | 10.1002/ijch.202000001 | es |
dc.journaltitle | Israel Journal of Chemistry | es |
dc.publication.volumen | 60 | es |
dc.publication.issue | 3-4 | es |
dc.publication.initialPage | 373 | es |
dc.publication.endPage | 393 | es |
dc.contributor.funder | Ministerio de Ciencia, Innovación y Universidades (MICINN). España | es |
dc.contributor.funder | Universidad Politécnica de Valencia | es |