dc.creator | Vázquez Domínguez, Pablo | es |
dc.creator | Journaud, Océane | es |
dc.creator | Vanthuyne, Nicolas | es |
dc.creator | Jacquemin, Denis | es |
dc.creator | Favereau, Ludovic | es |
dc.creator | Crassous, Jeanne | es |
dc.creator | Ros Lao, Abel | es |
dc.date.accessioned | 2022-11-03T16:05:23Z | |
dc.date.available | 2022-11-03T16:05:23Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Vázquez Domínguez, P., Journaud, O., Vanthuyne, N., Jacquemin, D., Favereau, L., Crassous, J. y Ros Lao, A. (2021). Helical donor–acceptor platinum complexes displaying dual luminescence and near-infrared circularly polarized luminescence. Dalton Transactions, 50 (38), 13220-13226. https://doi.org/10.1039/d1dt02184b. | |
dc.identifier.issn | 1477-9234 | es |
dc.identifier.uri | https://hdl.handle.net/11441/138678 | |
dc.description.abstract | A series of chiral platina[5]helicenes displaying dual luminescence,
i.e., fluorescence between 450 and 600 nm and red/NIR phosphorescence between 700 and 900 nm, has been synthesised, characterised and studied by first-principle calculations. This unusual behavior has been attributed to limited electronic interactions
between the d orbitals of the metal and the π-orbitals of the
organic ligand on the excited-state. Accordingly, the electron richness of the donor group on the helical ligand does not affect the
energy of the phosphorescence process but does play a role on its
efficiency. Interestingly, near-infrared circularly polarized luminescence can be obtained for the three complexes with dissymmetry
factors up to 3 × 10−3 at 750 nm. | es |
dc.format | application/pdf | es |
dc.format.extent | 7 p. | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry | es |
dc.relation.ispartof | Dalton Transactions, 50 (38), 13220-13226. | |
dc.rights | Atribución 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | * |
dc.title | Helical donor–acceptor platinum complexes displaying dual luminescence and near-infrared circularly polarized luminescence | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química orgánica | es |
dc.relation.projectID | PID2019-106358GB-C21 | es |
dc.relation.projectID | PID2019-106358GB-C22 | es |
dc.relation.publisherversion | https://dx.doi.org/10.1039/d1dt02184b | es |
dc.identifier.doi | 10.1039/d1dt02184b | es |
dc.journaltitle | Dalton Transactions | es |
dc.publication.volumen | 50 | es |
dc.publication.issue | 38 | es |
dc.publication.initialPage | 13220 | es |
dc.publication.endPage | 13226 | es |
dc.contributor.funder | Ministerio de Ciencia e Innovación (MICIN). España | es |
dc.contributor.funder | European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER) | es |
dc.contributor.funder | Junta de Andalucía | es |