dc.creator | Hernández Juárez, Martín | es |
dc.creator | López Serrano, Joaquín | es |
dc.creator | González Herrero, P. | es |
dc.creator | Rendón Márquez, Nuria | es |
dc.creator | Álvarez González, Eleuterio | es |
dc.creator | Paneque Sosa, Margarita | es |
dc.creator | Suárez Escobar, Andrés Luis | es |
dc.date.accessioned | 2022-10-27T11:35:49Z | |
dc.date.available | 2022-10-27T11:35:49Z | |
dc.date.issued | 2018 | |
dc.identifier.citation | Hernández Juárez, M., López Serrano, J., González Herrero, P., Rendón Márquez, N., Álvarez González, E., Paneque Sosa, M. y Suárez Escobar, A.L. (2018). Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment. Chemical Communications, 54, 3843-3846. https://doi.org/10.1039/C8CC00420J. | |
dc.identifier.issn | 1359-7345 | es |
dc.identifier.issn | 1364-548X | es |
dc.identifier.uri | https://hdl.handle.net/11441/138429 | |
dc.description.abstract | An iridium complex featuring a metalated lutidine-derived CNP
ligand reacts with KOt
Bu to yield a dimeric species with the two
metal centers bound to the opposite ligands through the CHN arms.
Furthermore, reaction with H2 in the presence of KOt
Bu of the same
iridium derivative results in the hydrogenation of the –CHQCH–
imidazolylidene moiety of the complex. NMR spectroscopy
monitoring of the latter reaction supports the initial formation of
a dihydride iridium complex containing an imidazolylidene ligand
fragment that is hydrogenated after prolonged reaction time. | es |
dc.description.sponsorship | Ministerio de Economía y Competitividad de España (MINECO) y fondos FEDER de la Unión Europea-CTQ2015-69568-P, CTQ2016-80814-R y CTQ2016- 81797-REDC | es |
dc.format | application/pdf | es |
dc.format.extent | 4 p. | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry | es |
dc.relation.ispartof | Chemical Communications, 54, 3843-3846. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment | es |
dc.type | info:eu-repo/semantics/article | es |
dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | CTQ2015-69568-P | es |
dc.relation.projectID | CTQ2016-80814-R | es |
dc.relation.projectID | CTQ2016-81797-REDC | es |
dc.relation.publisherversion | https://doi.org/10.1039/C8CC00420J | es |
dc.identifier.doi | 10.1039/C8CC00420J | es |
dc.journaltitle | Chemical Communications | es |
dc.publication.volumen | 54 | es |
dc.publication.initialPage | 3843 | es |
dc.publication.endPage | 3846 | es |
dc.contributor.funder | Ministerio de Economía y Competitividad (MINECO). España | es |
dc.contributor.funder | European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER) | es |