Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems

Hidalgo, Nereida; Moreno Díaz, Juan José; Pérez Jiménez, Marina; Maya Díaz, Celia María; López Serrano, Joaquín; Campos Manzano, Jesús

doi:10.1002/chem.201905793

Artículo

dc.creator	Hidalgo, Nereida	es
dc.creator	Moreno Díaz, Juan José	es
dc.creator	Pérez Jiménez, Marina	es
dc.creator	Maya Díaz, Celia María	es
dc.creator	López Serrano, Joaquín	es
dc.creator	Campos Manzano, Jesús	es
dc.date.accessioned	2022-10-24T15:43:21Z
dc.date.available	2022-10-24T15:43:21Z
dc.date.issued	2020
dc.identifier.citation	Hidalgo, N., Moreno Díaz, J.J., Pérez Jiménez, M., Maya Díaz, C.M., López Serrano, J. y Campos Manzano, J. (2020). Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems. Chemistry - A European Journal, 26 (27), 5982-5993. https://doi.org/10.1002/chem.201905793.
dc.identifier.issn	0947-6539	es
dc.identifier.issn	1521-3765	es
dc.identifier.uri	https://hdl.handle.net/11441/138289
dc.description.abstract	A joint experimental/computational effort to elucidate the mechanism of dihydrogen activation by a gold(I)/platinum(0) metal-only frustrated Lewis pair (FLP) is described herein. The drastic effects on H2 activation derived from subtle ligand modifications have also been investigated. The importance of the balance between bimetallic adduct formation and complete frustration has been interrogated, providing for the first time evidence for genuine metal-only FLP reactivity in solution. The origin of a strong inverse kinetic isotopic effect has also been clarified, offering further support for the proposed bimetallic FLP-type cleavage of dihydrogen.	es
dc.description.sponsorship	European Research Council 756575	es
dc.description.sponsorship	Ministerio de Economía y Competitividad CTQ2016-75193-P	es
dc.format	application/pdf	es
dc.format.extent	5993	es
dc.language.iso	eng	es
dc.publisher	Wiley-Blackwell	es
dc.relation.ispartof	Chemistry - A European Journal, 26 (27), 5982-5993.
dc.rights	Attribution-NonCommercial-NoDerivatives 4.0 Internacional	*
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/	*
dc.subject	Bimetallic complexes	es
dc.subject	Cooperative effects	es
dc.subject	Frustrated Lewis pairs	es
dc.subject	Hydrogen	es
dc.subject	Inverse kinetic isotopic effects	es
dc.title	Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems	es
dc.type	info:eu-repo/semantics/article	es
dcterms.identifier	https://ror.org/03yxnpp24
dc.type.version	info:eu-repo/semantics/acceptedVersion	es
dc.rights.accessRights	info:eu-repo/semantics/openAccess	es
dc.contributor.affiliation	Universidad de Sevilla. Departamento de Química Inorgánica	es
dc.relation.projectID	756575	es
dc.relation.projectID	CTQ2016-75193-P	es
dc.relation.publisherversion	https://doi.org/10.1002/chem.201905793	es
dc.identifier.doi	10.1002/chem.201905793	es
dc.journaltitle	Chemistry - A European Journal	es
dc.publication.volumen	26	es
dc.publication.issue	27	es
dc.publication.initialPage	5982
dc.publication.endPage	5993	es
dc.contributor.funder	European Research Council (ERC)	es
dc.contributor.funder	Ministerio de Economía y Competitividad (MINECO). España	es

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