dc.contributor.advisor | | |
dc.creator | Gil González, Eva | es |
dc.creator | Perejón Pazo, Antonio | es |
dc.creator | Sánchez Jiménez, Pedro Enrique | es |
dc.creator | Medina Carrasco, Santiago | es |
dc.creator | Kupčík, Jaroslav | es |
dc.creator | Šubrt, Jan | es |
dc.creator | Criado, José M. | es |
dc.creator | Pérez Maqueda, Luis Allan | es |
dc.date.accessioned | 2022-10-21T10:31:09Z | |
dc.date.available | 2022-10-21T10:31:09Z | |
dc.date.issued | 2018 | |
dc.identifier.citation | Gil González, E., Perejón Pazo, A., Sánchez Jiménez, P.E., Medina Carrasco, S., Kupčík, J., Šubrt, J.,...,Pérez Maqueda, L.A. (2018). Crystallization Kinetics of Nanocrystalline Materials by Combined X-ray Diffraction and Differential Scanning Calorimetry Experiments. Crystal Growth and Design, 18 (5), 3107-3116. https://doi.org/10.1021/acs.cgd.8b00241. | |
dc.identifier.issn | 1528-7483 | es |
dc.identifier.issn | 1528-7505 | es |
dc.identifier.uri | https://hdl.handle.net/11441/138226 | |
dc.description.abstract | Crystallization is one key aspect in the resulting
properties of nanocrystalline functional materials, and much
effort has been devoted to understanding the physical
mechanisms involved in these processes as a function of
temperature. The main problems associated with crystallization
kinetic studies come from the limitations of the employed
techniques, and the obtained results may vary significantly
depending on the choice of the measurement method. In this
work, a complete description of the thermal crystallization event
of nanocrystalline BiFeO3 has been performed by combining the
information obtained from three different experimental
techniques: in situ high-temperature X-ray diffraction, transmission electron microscopy, and differential scanning calorimetry. Interestingly, the kinetic analysis of the X-ray diffraction
and differential scanning calorimetry data yields almost identical results, although the physical properties measured by both
techniques are different. This allows the unambiguous determination of the kinetic parameters. The importance of a proper
definition of the conversion degree, which is limited by the employed measurement technique, is also highlighted. | es |
dc.description.sponsorship | Ministerio de Economía y Competitividad de España y fondos Feder de la Unión Europea (MINECOFEDER)-CTQ2014-52763-C2-1-R y CTQ2017-83602-C2 | es |
dc.format | application/pdf | es |
dc.format.extent | 10 p. | es |
dc.language.iso | eng | es |
dc.publisher | American Chemical Society | es |
dc.relation.ispartof | Crystal Growth and Design, 18 (5), 3107-3116. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.title | Crystallization Kinetics of Nanocrystalline Materials by Combined X-ray Diffraction and Differential Scanning Calorimetry Experiments | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | CTQ2014-52763-C2-1-R | es |
dc.relation.projectID | CTQ2017-83602-C2 | es |
dc.relation.publisherversion | https://doi.org/10.1021/acs.cgd.8b00241 | es |
dc.identifier.doi | 10.1021/acs.cgd.8b00241 | es |
dc.journaltitle | Crystal Growth and Design | es |
dc.publication.volumen | 18 | es |
dc.publication.issue | 5 | es |
dc.publication.initialPage | 3107 | es |
dc.publication.endPage | 3116 | es |
dc.contributor.funder | Ministerio de Economía y Competitividad (MINECO). España | es |
dc.contributor.funder | European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER) | es |