dc.creator | Hidalgo, Nereida | es |
dc.creator | Romero Pérez, Carlos | es |
dc.creator | Maya Díaz, Celia María | es |
dc.creator | Fernández, Israel | es |
dc.creator | Campos, Jesús | es |
dc.date.accessioned | 2022-09-09T11:58:26Z | |
dc.date.available | 2022-09-09T11:58:26Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Hidalgo, N., Romero Pérez, C., Maya Díaz, C.M., Fernández, I. y Campos, J. (2021). Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity. Organometallics, 40 (8), 1113-1119. | |
dc.identifier.issn | 1520-6041 | es |
dc.identifier.uri | https://hdl.handle.net/11441/136941 | |
dc.description.abstract | Metal-only Lewis pairs (MOLPs) based on zinc electrophiles are particularly interesting due to their relevance to Negishi cross-coupling reactions. Zinc-based ligands in bimetallic complexes also render unique reactivity to the transition metals at which they are bound. Here we explore the use of sterically hindered [Pt(PtBu3)2] (1) to access Pt/Zn bimetallic complexes. Compounds [(PtBu3)2Pt → Zn(C6F5)2] (2) and [Pt(ZnCp*)6] (3) (Cp* = pentamethylcyclopentadienyl) were isolated by reactions with Zn(C6F5)2 and [Zn2Cp*2], respectively. We also disclose the cooperative reactivity of 1/ZnX2 pairs (X = Cl, Br, I, and OTf) toward water and dihydrogen, which can be understood in terms of bimetallic frustration. | es |
dc.description.sponsorship | European Research Council (ERC) 756575 | es |
dc.description.sponsorship | Spanish Ministry of Science and Innovation (Projects PID2019-110856GA-I00, PID2019-106184GB-I00, and RED2018-102387-T) | es |
dc.format | application/pdf | es |
dc.format.extent | 7 p. | es |
dc.language.iso | eng | es |
dc.publisher | American Chemical Society | es |
dc.relation.ispartof | Organometallics, 40 (8), 1113-1119. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | 756575 | es |
dc.relation.projectID | PID2019-110856GA-I00 | es |
dc.relation.projectID | PID2019-106184GB-I00 | es |
dc.relation.projectID | RED2018-102387-T | es |
dc.relation.publisherversion | https://dx.doi.org/10.1021/acs.organomet.1c00088 | es |
dc.identifier.doi | 10.1021/acs.organomet.1c00088 | es |
dc.journaltitle | Organometallics | es |
dc.publication.volumen | 40 | es |
dc.publication.issue | 8 | es |
dc.publication.initialPage | 1113 | es |
dc.publication.endPage | 1119 | es |
dc.contributor.funder | European Research Council (ERC) | es |
dc.contributor.funder | Ministerio de Ciencia e Innovación (MICIN). España | es |