dc.creator | Fernández, José Antonio | es |
dc.creator | García, Juan Manuel | es |
dc.creator | Ríos Moreno, Pablo | es |
dc.creator | Rodríguez, Amor | es |
dc.date.accessioned | 2022-08-09T11:09:58Z | |
dc.date.available | 2022-08-09T11:09:58Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Fernández, J.A., García, J.M., Ríos Moreno, P. y Rodríguez, A. (2021). Hydrosilylation of Carbonyl Compounds Catalyzed by a Nickel Complex Bearing a PBP Ligand. European Journal of Inorganic Chemistry, 2021 (29), 2993-2998. | |
dc.identifier.issn | 1099-0682 | es |
dc.identifier.uri | https://hdl.handle.net/11441/136076 | |
dc.description.abstract | The efficient catalytic hydrosilylation of ketones and aldehydes has been investigated using a nickel pincer hydride complex supported by a diphosphino-boryl ligand (PBP). It was found that the presence of the boryl group within the skeleton of the ligand has a beneficial effect on the catalytic activities observed for ketones compared to related pincer systems. The analysis of the reaction mechanism allows for the synthesis and characterization of a nickel alkoxide derivative by insertion of the carbonyl moiety into the Ni−H bond. Combined experimental and theoretical analysis (DFT) support a reaction mechanism that involves the initial formation of an alkoxide complex followed by reaction with the silane to release the corresponding silyl ether and regenerate the catalyst. | es |
dc.description.sponsorship | MINECO PID2019-109312GB-IOO and RED2018-102387-T | es |
dc.description.sponsorship | CSIC AEPP-CTQ2016-76267-P | es |
dc.format | application/pdf | es |
dc.format.extent | 5 p. | es |
dc.language.iso | eng | es |
dc.publisher | Wiley | es |
dc.relation.ispartof | European Journal of Inorganic Chemistry, 2021 (29), 2993-2998. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Hydrosilylation of Carbonyl Compounds Catalyzed by a Nickel Complex Bearing a PBP Ligand | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | PID2019-109312GB-IOO | es |
dc.relation.projectID | RED2018-102387-T | es |
dc.relation.projectID | AEPP-CTQ2016-76267-P | es |
dc.relation.publisherversion | https://dx.doi.org/10.1002/ejic.202100425 | es |
dc.identifier.doi | 10.1002/ejic.202100425 | es |
dc.journaltitle | European Journal of Inorganic Chemistry | es |
dc.publication.volumen | 2021 | es |
dc.publication.issue | 29 | es |
dc.publication.initialPage | 2993 | es |
dc.publication.endPage | 2998 | es |
dc.contributor.funder | Ministerio de Economia, Industria y Competitividad (MINECO). España | es |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (CSIC) | es |