dc.creator | Bajo Velázquez, Sonia | es |
dc.creator | Alcaide, María M. | es |
dc.creator | López Serrano, Joaquín | es |
dc.creator | Campos, Jesús | es |
dc.date.accessioned | 2022-07-01T12:32:10Z | |
dc.date.available | 2022-07-01T12:32:10Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Bajo Velázquez, S., Alcaide, M.M., López Serrano, J. y Campos, J. (2021). Dehydrogenative Double C−H Bond Activation in a Germylene-Rhodium Complex. Chemistry: A European Journal, 27 (66), 16422-16428. | |
dc.identifier.issn | 1521-3765 | es |
dc.identifier.uri | https://hdl.handle.net/11441/134927 | |
dc.description.abstract | Transition metal tetrylene complexes offer great opportunities for molecular cooperation due to the ambiphilic character of the group 14 element. Here we focus on the coordination of germylene [(ArMes2)2Ge :] (ArMes=C6H3-2,6-(C6H2-2,4,6-Me3)2) to [RhCl(COD)]2 (COD=1,5-cyclooctadiene), which yields a neutral germyl complex in which the rhodium center exhibits both η6- and η2-coordination to two mesityl rings in an unusual pincer-type structure. Chloride abstraction from this species triggers a singular dehydrogenative double C−H bond activation across the Ge/Rh motif. We have isolated and fully characterized three rhodium-germyl species associated to three C−H cleavage events along this process. The reaction mechanism has been further investigated by computational means, supporting the key cooperative action of rhodium and germanium centers. | es |
dc.description.sponsorship | European Research Council 756575 | es |
dc.description.sponsorship | Junta de Andalucia P18-FR-4688 | es |
dc.format | application/pdf | es |
dc.format.extent | 7 p. | es |
dc.language.iso | eng | es |
dc.publisher | Wiley | es |
dc.relation.ispartof | Chemistry: A European Journal, 27 (66), 16422-16428. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Dehydrogenative Double C−H Bond Activation in a Germylene-Rhodium Complex | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | 756575 | es |
dc.relation.projectID | P18-FR-4688 | es |
dc.relation.publisherversion | https://dx.doi.org/10.1002/chem.202102529 | es |
dc.identifier.doi | 10.1002/chem.202102529 | es |
dc.journaltitle | Chemistry: A European Journal | es |
dc.publication.volumen | 27 | es |
dc.publication.issue | 66 | es |
dc.publication.initialPage | 16422 | es |
dc.publication.endPage | 16428 | es |
dc.contributor.funder | European Research Council (ERC) | es |
dc.contributor.funder | Junta de Andalucía | es |