dc.creator | Pérez Jiménez, Marina | es |
dc.creator | Campos, Jesús | es |
dc.creator | Jover, Jesús | es |
dc.creator | Álvarez, Santiago | es |
dc.creator | Carmona Guzmán, Ernesto | es |
dc.date.accessioned | 2022-03-23T13:12:49Z | |
dc.date.available | 2022-03-23T13:12:49Z | |
dc.date.issued | 2022 | |
dc.identifier.citation | Pérez Jiménez, M., Campos, J., Jover, J., Álvarez, S. y Carmona Guzmán, E. (2022). Supported σ-Complexes of Li−C Bonds from Coordination of Monomeric Molecules of LiCH3, LiCH2CH3 and LiC6H5 to Mo≣Mo Bonds. Angewandte Chemie, 61 (8), e202116009. | |
dc.identifier.issn | 1433-7851 (print) | es |
dc.identifier.issn | 1521-3773 (online) | es |
dc.identifier.uri | https://hdl.handle.net/11441/131190 | |
dc.description.abstract | LiCH3 and LiCH2CH3 react with the complex [Mo2(H)2(μ-AdDipp2)2(thf)2] (1⋅thf) with coordination of two molecules of LiCH2R (R=H, CH3) and formation of complexes [Mo2{μ-HLi(thf)CH2R}2(AdDipp2)2], 5⋅LiCH3 and 5⋅LiCH2CH3, respectively (AdDipp2=HC(NDipp)2; Dipp=2,6-iPr2C6H3; thf=C4H8O). Due to steric hindrance, only one molecule of LiC6H5 adds to 1⋅thf generating the complex [Mo2(H){μ-HLi(thf)C6H5}(μ-AdDipp2)2], (4⋅LiC6H5). Computational studies disclose the existence of five-center six-electron bonding within the H−Mo≣Mo−C−Li metallacycles, with a mostly covalent H−Mo≣Mo−C group and predominantly ionic Li−C and Li−H interactions. However, the latter bonds exhibit non-negligible covalency, as indicated by X-ray, computational data and the large one-bond 6,7Li,1H and 6,7Li,13C NMR coupling constants found for the three-atom H−Li−C chains. By contrast, the phenyl group in 4⋅LiC6H5 coordinates in an η2 fashion to the lithium atom through the ipso and one of the ortho carbon atoms. | es |
dc.description.sponsorship | Ministry of Economy and Competitiveness (PID2019-110856GA-I00 and PGC2018-093863-B-C21) | es |
dc.description.sponsorship | Spanish Structures of Excellence María de Maeztu program (grant MDM-2017-0767) | es |
dc.description.sponsorship | Generalitat de Catalunya– AGAUR (grant 2017-SGR-1289) | es |
dc.format | application/pdf | es |
dc.format.extent | 10 p. | es |
dc.language.iso | eng | es |
dc.publisher | German Chemical Society | es |
dc.relation.ispartof | Angewandte Chemie, 61 (8), e202116009. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Supported σ-Complexes of Li−C Bonds from Coordination of Monomeric Molecules of LiCH3, LiCH2CH3 and LiC6H5 to Mo≣Mo Bonds | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | PID2019-110856GA-I00 | es |
dc.relation.projectID | PGC2018-093863-B-C21 | es |
dc.relation.projectID | MDM-2017-0767 | es |
dc.relation.projectID | 2017-SGR-1289 | es |
dc.relation.publisherversion | http://dx.doi.org/10.1002/anie.202116009 | es |
dc.identifier.doi | 10.1002/anie.202116009 | es |
dc.journaltitle | Angewandte Chemie | es |
dc.publication.volumen | 61 | es |
dc.publication.issue | 8 | es |
dc.publication.initialPage | e202116009 | es |
dc.contributor.funder | Ministerio de Economía y Competitividad (MINECO). España | es |
dc.contributor.funder | Generalitat de Catalunya | es |