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Listar Artículos (Instituto de Investigaciones Químicas (IIQ) – CIC Cartuja) por autor "Álvarez González, Eleuterio"
Mostrando ítems 21-40 de 45
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Hydrogenation of imines catalysed by ruthenium(ii) complexes based on lutidine-derived CNC pincer ligands
Hernández Juárez, Martín; Vaquero Gutiérrez, Mónica; Álvarez González, Eleuterio; Salazar Pereda, Verónica; Suárez Escobar, Andrés Luis (Royal Society of Chemistry (Great Britain), 2013)The preparation of new Ru(ii) complexes incorporating fac-coordinated lutidine-derived CNC ligands is reported. These ...
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Investigations on the Coupling of Ethylene and Alkynes in Tp Me2 Ir Compounds: Water as an Effective Trapping Agent
Álvarez González, Eleuterio; Paneque Sosa, Margarita; Martín Posadas, Cristina Isabel; López Poveda, Manuel; Rendón Márquez, Nuria; Mereiter, Kurt (Wiley-VCH, 2007)The reaction of the bis(ethylene) complex [TpMe2Ir(C2H4)2] (1) (TpMe: hydrotris(3,5-dimethylpyrazolyl)borate) with two ...
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Lithium Di-‐ and Trimethyl Dimolybdenum(II) Complexes with Mo-‐Mo Quadruple Bonds and Bridging Methyl Groups
Curado, Natalia; Carrasco, Mario; Álvarez González, Eleuterio; Maya Díaz, Celia María; Peloso, Riccardo; Rodríguez, Amor; López Serrano, Joaquín; Carmona Guzmán, Ernesto (American Chemical Society, 2015)New dimolybdenum complexes of composition [Mo2{μ-Me}2Li(S)}(μ- X)(μ-N^N)2] (3a−3c), where S = THF or Et2O and N^N represents ...
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Mechanism of Alkyl Migration in Diorganomagnesium 2,6-Bis(imino)pyridine Complexes: Formation of Grignard-Type Complexes with Square-Planar Mg(II) Centers
Sandoval, John J.; Palma, Pilar; Álvarez González, Eleuterio; Cámpora Pérez, Juan; Rodríguez Delgado, Antonio (American Chemical Society, 2016)Dialkylmagnesium compounds [MgR2L2] (R = n-Bu, L = none or R = Bn, L = THF) react with 2,6-bis(imino)pyridines (BIP) to ...
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Artículo
Migratory insertion reactions of nickel and palladium σ-alkyl complexes with a phosphinito-imine ligand†‡
Ortíz de la Tabla González, Laura; Matas Ruíz, Inmaculada; Álvarez González, Eleuterio; Cámpora Pérez, Juan (Royal Society of Chemistry (Great Britain), 2012)Ligand exchange reactions have been used for the synthesis of metallacyclic complexes of Ni and Pd of the type [M[upper ...
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N-substituted Aminobiphenyl Palladacycles Stabilized by Dialkylterphenyl Phosphanes: Preparation and Applications in C[sbnd]N Cross-coupling Reactions
Monti, Andrea; Jiménez Rama, Raquel; Gómez, Beatriz; Maya Díaz, Celia María; Álvarez González, Eleuterio; Carmona Guzmán, Ernesto; Nicasio Jaramillo, María del Carmen (Elsevier, 2021)Neutral and cationic N-methyl- and N-phenyl-2-aminobiphenyl methanesulfonate palladacycles stabilized with dialkylterphenyl ...
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Neutral Bis(imino)-1,4-dihydropyridinate and Cationic Bis(imino)pyridine σ-Alkylzinc(II) Complexes as Hydride Exchange Systems: Classic Organometallic Chemistry Meets Ligand-Centered, Biomimetic Reactivity
Sandoval, John J.; Álvarez González, Eleuterio; Palma Ramírez, María del Pilar; Rodríguez Delgado, Antonio; Cámpora Pérez, Juan (American Chemical Society, 2018)The 1,4-dihydropyridinate complex [(4-BnHBIP)Zn(Bn)], readily available through the highly selective reaction of a ...
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Nickel and Palladium Complexes with New Phosphinito-Imine Ligands and Their Application as Ethylene Oligomerization Catalysts
Ortiz de la Tabla González, Laura; Matas Ruíz, Inmaculada; Palma Ramírez, María del Pilar; Álvarez González, Eleuterio; Cámpora Pérez, Juan (American Chemical Society, 2012)Phosphinito-imines, a new class of P,N donors, are readily generated by reaction of bulky arylamide anions [R2CONAr]− (R2 ...
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Artículo
Novel bis (1,3,2-diazaphospholidine) ligands for asymmetric catalysis
Arribas Nieto, Inmaculada; Álvarez González, Eleuterio; Pizzano Mancera, Antonio (American Chemical Society, 2013)A family of modularly designed chiral bis(1,3,2-diazaphospholidines) with N-aryl substituents (NP-PN) is reported. These ...
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Oxygen-Induced Dimerization of Alkyl-Manganese(II) 2,6-Bisiminopyridine Complexes: Selective Synthesis of a New Ditopic NNN-Pincer Ligand
Sandoval, John J.; Melero, Cristobal; Palma, Pilar; Álvarez González, Eleuterio; Rodríguez Delgado, Antonio; Cámpora Pérez, Juan (American Chemical Society, 2016)The outcome of the reaction of manganese(II) dialkyls with 2,6-bisiminopyridine (BIP) ligands is dramatically altered by ...
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Protonolysis of Fe-C bonds of a diiminopyridineiron(II) dialkyl complex by acids of different strengths: Influence of monoanionic ligands on the spectroscopic properties of diiminopyiridine-FeY2 complexes
Cartes Domínguez, María Ángeles; Palma Ramírez, María del Pilar; Sandoval Valencia, John Jairo; Cámpora Pérez, Juan; Álvarez González, Eleuterio (Elsevier, 2014)The reaction of the dialkyliron complex [Fe(CH2SiMe 3)2(MesBIP)] (MesBIP = 2,6-bis((N-mesityl)acetimidoyl)pyridine) with ...
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Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites
Carrasco, Mario; Faust, Michelle; Peloso, Riccardo; Rodríguez Iglesias, María Amor; López Serrano, Joaquín; Álvarez González, Eleuterio; Maya Díaz, Celia María; Power, Philip P.; Carmona Guzmán, Ernesto (Royal Society of Chemistry (Great Britain), 2012)New quadruply bonded dimolybdenum complexes of the terphenyl ligand Ar Xyl2 (Ar Xyl2 = C 6H 3-2,6-(C 6H 3-2,6-Me 2) 2) ...
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Artículo
Reactivity of TpMe2-containing hydride-iridafurans with alkenes, alkynes, and H2
Vivancos Ureña, Ángela; Martín Posadas, Cristina Isabel; Hernández, Yohar A.; Rendón Márquez, Nuria; García Rubín, Silvia; Álvarez González, Eleuterio; Paneque Sosa, Margarita; López Poveda, Manuel (American Chemical Society, 2014)The TpMe2-containing hydride-iridafurans 2a,b (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate) cleanly reacted with ethylene ...
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Artículo
Ruthenium(II) Complexes Containing Lutidine-derived Pincer CNC Ligands: Synthesis, Structure and Catalytic Hydrogenation of C=N bonds
Hernández Juárez, Martín; López Serrano, Joaquín; Lara Muñoz, Patricia; Morales Cerón, Judith; Vaquero Gutiérrez, Mónica; Álvarez González, Eleuterio; Salazar Pereda, Verónica; Suárez Escobar, Andrés Luis (Wiley-Blackwell, 2015)A series of Ru complexes containing lutidine‐derived pincer CNC ligands have been prepared by transmetalation with the ...
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Sequential reduction and alkyl exchange reactions of bis(imino)pyridine dialkyliron(II) with trimethylaluminum
Cartes Domínguez, María Ángeles; Rodríguez Delgado, Antonio; Palma Ramírez, María del Pilar; Álvarez González, Eleuterio (American Chemical Society, 2014)The sequence of reactions ensuing when the 2,6-bis(imino)pyridine Fe(II) dialkyl complexes [Fe(CH2SiMe3)2(BIP)] react with ...
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Synthesis and characterization of enantiopure chiral NH2/SO palladium complexes
Moreno Rodríguez, Nazaret; Borrego Sánchez de la Cuesta, Lorenzo Gabriel; Recio Jiménez, Rocío; Valdivia Giménez, Victoria Esther; Nicasio Jaramillo, María del Carmen; Álvarez González, Eleuterio; Khiar, Noureddine; Fernández Fernández, Inmaculada (Royal Society of Chemistry, 2023)A series of enantiopure chiral NH2/SO palladium complexes have been synthesised with high yields by treating the corresponding ...
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Synthesis and reactivity of half-sandwich (η 5 -C 5 Me 5 )Ir(iii) complexes of a cyclometallated aryl phosphine ligand
Campos Manzano, Jesús; Álvarez González, Eleuterio; Carmona Guzmán, Ernesto (Royal Society of Chemistry, 2011)Reaction of the Ir(iii) dimer [(η 5 -C 5 Me 5 )IrCl 2 ] 2 with PMeXyl 2 (Xyl = 2,6-C 6 H 3 Me 2 ), in the presence of the ...
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Artículo
Synthesis and Reactivity of Nickel an Palladium Fluoride Complexes with PCP Pincer Ligands. A NMR-Based Assessment of Electron-Donating Properties of Fluoride and Other Monoanionic Ligands
Martínez Prieto, Luis Miguel; Melero Jiménez, Cristóbal; Rio Díaz-Jara, Diego del; Cámpora Pérez, Juan; Álvarez González, Eleuterio (American Chemical Society, 2012)A series of complexes of the type [(iPrPCP)M-L] (M = Ni, Pd), containing the 2,6-bis(diisopropylphosphinomethyl)phenyl ...
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Synthesis and Reactivity toward H2 of (h5- C5Me5)Rh(III) Complexes with Bulky Aminopyridinate Ligands
Zamorano Márquez, Ana; Rendón Márquez, Nuria; Vaspuesta, José E.V.; Álvarez González, Eleuterio; Carmona Guzmán, Ernesto (American Chemical Society, 2015)Electrophilic, cationic Rh(III) complexes of composition [(η5-C5Me5)Rh(Ap)]+, (1+), were prepared by reaction of ...
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Artículo
Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2, 2 ':6 ', 2''-terpyridine
Paneque Sosa, Margarita; López Poveda, Manuel; Vattier Lagarrigue, María Florencia; Álvarez González, Eleuterio; Carmona Guzmán, Ernesto (Royal Society of Chemistry, 2009)Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ...