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Artículo
Overlooked pitfalls in CaO carbonation kinetics studies nearby equilibrium: Instrumental effects on calculated kinetic rate constants
(Elsevier, 2022)
Due to its technological applications, such as CO2 capture, CaO carbonation kinetics has been extensively studied using a wide array of methods and experimental conditions. A complete understanding of carbonation kinetics ...
Artículo
Monomeric alkoxide and alkylcarbonate complexes of nickel and palladium stabilized with the iPrPCP pincer ligand: a model for the catalytic carboxylation of alcohols to alkyl carbonates
(Royal Society of Chemistry, 2019)
Monomeric alkoxo complexes of the type [(iPrPCP)M-OR] (M = Ni or Pd; R = Me, Et, CH2CH2OH; iPrPCP = 2,6-bis(diisopropylphosphino)phenyl) react rapidly with CO2 to afford the corresponding alkylcarbonates [(iPrPCP)M-OCOOR]. ...
Artículo
Tailoring structured WGS catalysts: Impact of multilayered concept on the water surface interactions
(Elsevier, 2018)
A novel multilayer approach for designing structured WGS catalyst is employed in this study as a response to the lack of new strategies in the literature. The approach proposes the use of two successive layers with ...
Artículo
σ-Silane Platinum(II) Complexes as Intermediates in C−Si Bond-Coupling Processes
(Wiley, 2019)
Platinum complexes [Pt(NHC’)(NHC)][BArF] (NHC’ denotes the cyclometallated N-heterocyclic carbene ligand, NHC) react with primary silanes RSiH3 leading to the cyclometallated platinum(II) silyl complexes [Pt(NHC-SiHR’ ...
Artículo
Enhancing the catalytic properties of well-defined electrophilic platinum complexes
(Royal Society of Chemistry, 2020)
Platinum complexes have been often considered as the least reactive of the group 10 triad metals. Slow kinetics are behind this lack of reactivity but, still, some industrially relevant catalytic process are dominated by ...
Artículo
Electrical properties of bismuth ferrites: Bi2Fe4O9 and Bi25FeO39
(Elsevier, 2019)
Bi2Fe4O9 was prepared by solid-state reaction and the electrical properties measured by impedance spectro- scopy. After annealing in O2 at 900 °C, Bi2Fe4O9 is an electrically-homogeneous insulator. Its high frequency p ...