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Artículo
Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment
(Royal Society of Chemistry, 2018)
An iridium complex featuring a metalated lutidine-derived CNP ligand reacts with KOt Bu to yield a dimeric species with the two metal centers bound to the opposite ligands through the CHN arms. Furthermore, reaction ...
Artículo
Gold catalyst recycling study in base-free glucose oxidation reaction
(Elsevier, 2018)
This work is devoted to the study of viability of immobilized gold colloids on carbon as catalysts for the base-free glucose oxidation reaction with a special emphasis made on catalysts’ recycling, operational life and ...
Artículo
Influence of the ionic liquid presence on the selective oxidation of glucose over molybdenum based catalysts
(Elsevier, 2016-12-01)
Two different approaches are proposed in this work in order to study the influence of the ionic liquid presence in the reaction of glucose oxidation by H2O2 in mild conditions. The ionic liquids are applied either as a ...
Artículo
Coordination of LiH Molecules to Mo≣Mo Bonds: Experimental and Computational Studies on Mo2LiH2, Mo2Li2H4, and Mo6Li9H18 Clusters
(American Chemical Society, 2021)
The reactions of LiAlH4 as the source of LiH with complexes that contain (H)Mo≣Mo and (H)Mo≣Mo(H) cores stabilized by the coordination of bulky AdDipp2 ligands result in the respective coordination of one and two molecules ...
Artículo
Influence of ball milling on CaO crystal growth during limestone and dolomite calcination: Effect on CO2 capture at Calcium Looping conditions
(American Chemical Society, 2016)
The multicycle CO2 capture performance of CaO derived from the calcination of ball-milled limestone and dolomite have been tested under high temperature and high CO2 concentration environment for the first time. Here it ...
Artículo
Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs
(American Chemical Society, 2020)
Introducing transition metals into frustrated Lewis pair systems has attracted considerable attention in recent years. Here we report a selection of three metal-only frustrated systems based on Au(I)/Pt(0) combinations and ...
Artículo
Relevant influence of limestone crystallinity on CO2 capture in the Ca-looping technology at realistic calcination conditions
(American Chemical Society, 2014)
We analyze the role of limestone crystallinity on its CO2 capture performance when subjected to carbonation/calcination cycles at conditions mimicking the Ca-looping (CaL) technology for postcombustion CO 2 capture. The ...
Artículo
Limestone calcination nearby equilibrium: Kinetics, CaO crystal structure, sintering and reactivity
(American Chemical Society, 2015)
In this work, we analyze limestone calcination kinetics at environmental conditions involving a CO2 partial pressure P close to the equilibrium pressure Peq by means of in situ X-ray diffraction (XRD) and thermogravimetric ...
Artículo
Mono and bimetallic Cu-Ni structured catalysts for the water gas shift reaction
(Elsevier, 2015)
The water-gas shift (WGS) reaction over structured Cu, Ni, and bimetallic Cu-Ni supported on active carbon (AC) catalysts was investigated. The structured catalysts were prepared in pellets form and applied in the medium ...
Artículo
Effect of heat pretreatment/recarbonation in the Ca-looping process at realistic calcination conditions
(American Chemical Society, 2014)
Even though an increasing number of pilot-scale plants are demonstrating the potential efficiency of the Ca-looping technology to capture CO2 at a commercial level, a still standing matter of concern is the loss of carbonation ...