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Mostrando ítems 21-30 de 31
Artículo
Oxidation of CO over gold supported on Zn-modified ceria catalysts
(Elsevier, 2011)
A series of Zn-modified ceria solids were prepared by thermal decomposition of the corresponding metal propionates. The formation of segregated ZnO particles on the ceria surface is evidenced for these solids using X-ray ...
Artículo
H2 oxidation as criterion for PrOx catalyst selection: Examples based on Au-CoOx-supported systems
(Elsevier, 2015-06-01)
A new approach for understanding PrOx reaction over gold catalysts is proposed in this work. The competition between H2 and CO oxidation has been studied over a series of Au/MOx/Al2O3 (M = Ce and Co) catalysts in simulated ...
Artículo
Sustainable routes for acetic acid production: Traditional processes vs a low-carbon, biogas-based strategy
(Elsevier, 2022)
The conversion of biogas, mainly formed of CO2 and CH4, into high-value platform chemicals is increasing attention in a context of low-carbon societies. In this new paradigm, acetic acid (AA) is deemed as an interesting ...
Artículo
Synthesis and application of layered titanates in the photocatalytic degradation of phenol
(Elsevier, 2015)
This study proposes a direct synthetic route to single titanate sheets through the mild and versatile conditions of the >chimie douce>. The stages of the production include the complexation of the titanium alkoxide precursor ...
Artículo
Preferential oxidation of CO over Au/CuOx-CeO2 catalyst in microstructured reactors studied through CFD simulations
(Elsevier, 2013)
A computational fluid dynamics (CFD) simulation study of the preferential oxidation of CO (CO-PROX) in microstructured reactors consisting in square and semicircular microchannels coated with anAu/CuOx¿CeO2catalyst is ...
Artículo
Pt vs. Au in water-gas shift reaction
(Elsevier, 2014)
This work presents a comparison of the gold- and platinum-based catalysts behavior in the water-gas shift (WGS) reaction. The influence of the support, e.g., its composition and electronic properties, studied in detail by ...
Artículo
Fe-doped ceria solids synthesized by the microemulsion method for CO oxidation reactions
(Elsevier, 2011)
A series of Ce-Fe mixed oxides as well as the pure oxides were synthesized by the microemulsions method. The solid solution formation was established for all the Fe-doped systems and only a hardly noticeable segregation ...
Artículo
Au/CeO2-ZnO/Al2O3 as Versatile Catalysts for Oxidation Reactions: Application in Gas/Liquid Environmental Processes
(Frontiers Media, 2019)
The present work showcases the versatility of nanogold systems supported on Zn-doped ceria when applied in two important environmental processes, the total CO oxidation, and the liquid phase oxidation of glucose to ...
Artículo
Highly Dispersed Rh Single Atoms over Graphitic Carbon Nitride as a Robust Catalyst for the Hydroformylation Reaction
(Royal Society of Chemistry, 2023)
Rhodium-catalysed hydroformylation, effective tool in bulk and fine-chemical synthesis, predominantly uses soluble metal complexes. For that reason, the metal leaching and the catalyst recycling are still the major drawbacks ...
Artículo
Development of Power-to-X Catalytic Processes for CO2 Valorisation: From the Molecular Level to the Reactor Architecture
(Multidisciplinary Digital Publishing Institute (MDPI), 2022)
Nowadays, global climate change is likely the most compelling problem mankind is facing. In this scenario, decarbonisation of the chemical industry is one of the global challenges that the scientific community needs to ...