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Artículo
Iron-modified ceria and Au/ceria catalysts for Total and Preferential Oxidation of CO (TOX and PROX)
(Elsevier, 2010)
Iron-modified ceria supports containing different molar percentages of Fe (0%, 10%, 25%, and 50%) were synthesized by thermal decomposition of the metal propionates. The formation of a Ce-Fe oxide solid solution is evidenced ...
Artículo
Influence of the O2/CO ratio and the presence of H2O and CO2 in the feed-stream during the preferential oxidation of CO (PROX) over a CuOx/CeO2-coated microchannel reactor
(Elsevier, 2013)
The catalytic performance of a CuOx/CeO2 powder catalyst and that of a microchannel reactor or microreactor (MR) coated with the same solid was determined and compared. The catalytic activity measurements were carried out ...
Artículo
Gold supported on metal-doped ceria catalysts (M = Zr, Zn and Fe) for the preferential oxidation of CO (PROX)
(Academic Press, 2010)
A series of ceria oxides doped with 10 mol.% of Zr, Zn and Fe have been prepared by a pseudo sol-gel method throughout the thermal decomposition of the corresponding metallic propionates. With these supports, 1 wt.% gold ...
Artículo
Selective CO removal over Au/CeFe and CeCu catalysts in microreactors studied through kinetic analysis and CFD simulations
(Elsevier, 2011)
A kinetic study of the preferential oxidation of CO in H2 rich streams (CO-PrOx) over a cerium-copper oxide (CeCu) and a gold catalyst supported on cerium-iron oxide (Au/CeFe) is presented. The gold catalyst is very active ...
Artículo
Preferential oxidation of CO (CO-PROX) over CuOx/CeO2 coated microchannel reactor
(Elsevier, 2012)
The general aspects of the synthesis and characterization results of a CuOx/CeO2 catalyst were presented. In addition the principal steps for manufacturing a microchannel reactor and for the coating of the CuOx/CeO2 catalyst ...
Artículo
Design and testing of a microchannel reactor for the PROX reaction
(Elsevier, 2011)
The different steps for manufacturing a microchannel reactor for the PROX reaction are discussed. Transient Liquid Phase bonding (TLP) using a Ni-B-Si amorphous melt spun is used for joining micromilled Al-alloyed ferritic ...
Artículo
Oxidation of CO over gold supported on Zn-modified ceria catalysts
(Elsevier, 2011)
A series of Zn-modified ceria solids were prepared by thermal decomposition of the corresponding metal propionates. The formation of segregated ZnO particles on the ceria surface is evidenced for these solids using X-ray ...
Artículo
Preferential oxidation of CO over Au/CuOx-CeO2 catalyst in microstructured reactors studied through CFD simulations
(Elsevier, 2013)
A computational fluid dynamics (CFD) simulation study of the preferential oxidation of CO (CO-PROX) in microstructured reactors consisting in square and semicircular microchannels coated with anAu/CuOx¿CeO2catalyst is ...
Artículo
Fe-doped ceria solids synthesized by the microemulsion method for CO oxidation reactions
(Elsevier, 2011)
A series of Ce-Fe mixed oxides as well as the pure oxides were synthesized by the microemulsions method. The solid solution formation was established for all the Fe-doped systems and only a hardly noticeable segregation ...